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- W2735532933 endingPage "12667" @default.
- W2735532933 startingPage "12655" @default.
- W2735532933 abstract "Abstract Experimental and computational efforts are reported which illuminate the mechanism of a novel boron version of the widespread Negishi coupling reaction that offers a new protocol for the formation of aryl/acyl C−B bonds using a bulky boryl fragment. The role of nucleophilic borylzinc reagents in the reduction of the Pd II pre‐catalysts to Pd 0 active species has been demonstrated. The non‐innocent behavior of the PPh 3 ligands of the [Pd(PPh 3 ) 2 Cl 2 ] pre‐catalyst under activation conditions has been probed both experimentally and computationally, revealing the formation of a trimetallic Pd species bearing bridging phosphide (PPh 2 − ) ligands. Our studies also reveal the monoligated formulation of the Pd 0 active species, which led us to synthesize related (η 3 ‐indenyl)Pd‐monophosphine catalysts which show improved catalytic performances under mild conditions. A complete mechanistic proposal to aid future catalyst developments is provided." @default.
- W2735532933 created "2017-07-21" @default.
- W2735532933 creator A5007266295 @default.
- W2735532933 creator A5015045788 @default.
- W2735532933 creator A5041997481 @default.
- W2735532933 creator A5078208746 @default.
- W2735532933 date "2017-08-10" @default.
- W2735532933 modified "2023-10-17" @default.
- W2735532933 title "A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction" @default.
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