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• W2735652912 abstract "Abstract The oxo-bridged azaallylzirconium chlorides (μ-O){η3-(2,6-Et2-4-R-C6H2) N(Ph)CCHSiMe2NMe2ZrCl2}2, [R = Me (C1) and H (C2)] have been prepared in reasonable yields from the reactions of zirconium tetrachloride and the correspondent ligands, Me2NMe2SiCH2(Ph)CN(2,6-Et2-4-R-C6H2). The representative complex C1 was crystallized and identified by the single-crystal X-ray diffraction, indicating oxo-bridged dinuclear azaallylzirconium structure. Both azaallylzirconium complexes exhibited notable catalytic activities toward ethylene polymerization in the presence of MAO, and obtained polyethylenes possess high molecular weights." @default.
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• W2735652912 date "2017-09-01" @default.
• W2735652912 modified "2023-09-22" @default.
• W2735652912 title "Oxo-bridged azaallylzirconium complexes: Synthesis, characterization and ethylene polymerization behavior" @default.
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• W2735652912 doi "https://doi.org/10.1016/j.ica.2017.07.017" @default.
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