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- W2735672211 abstract "Abstract The present study aims to consolidate information regarding the catalytic reaction mechanism of MgH 2 /TiO 2 hydrogen storage system. Reduction of titania, resulting to evolution of a monoxide rock salt nanocrystalline phase was identified by in-situ X-ray diffraction (XRD) study of a 3 mol% TiO 2 additive mixed MgH 2 . Existence of homogeneously distributed Ti in a crystalline rock salt matrix was confirmed by combined analysis of X – ray diffraction (XRD), high resolution transmission electron microscopy (HRTEM) and elemental chemical mapping techniques. Moreover, titanium in Ti 3+ and Ti 2+ valance states was confirmed by X - ray photoelectron spectroscopy (XPS). Differential scanning calorimetry (DSC) study proves that the reduced Ti oxide phases promote the low temperature dehydrogenation of MgH 2 . The present observations reiterate that the MgO rock salt layer existing in oxide additives loaded MgH 2 is not necessarily a barrier layer that blocks the diffusion of hydrogen." @default.
- W2735672211 created "2017-07-21" @default.
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- W2735672211 date "2017-09-01" @default.
- W2735672211 modified "2023-10-18" @default.
- W2735672211 title "Evolution of reduced Ti containing phase(s) in MgH 2 /TiO 2 system and its effect on the hydrogen storage behavior of MgH 2" @default.
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- W2735672211 doi "https://doi.org/10.1016/j.jpowsour.2017.07.032" @default.
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