Matches in SemOpenAlex for { <https://semopenalex.org/work/W2735758330> ?p ?o ?g. }
- W2735758330 endingPage "8792" @default.
- W2735758330 startingPage "8782" @default.
- W2735758330 abstract "Blue-colored molybdenum oxide nitrides of the Mo2(O,N,□)5 type were synthesized by direct nitridation of commercially available molybdenum trioxide with a mixture of gaseous ammonia and oxygen. Chemical composition, crystal structure, and stability of the obtained and hitherto unknown compounds are studied extensively. The average oxidation state of +5 for molybdenum is proven by Mo K near-edge X-ray absorption spectroscopy; the magnetic behavior is in agreement with compounds exhibiting MoVO6 units. The new materials are stable up to ∼773 K in an inert gas atmosphere. At higher temperatures, decomposition is observed. X-ray and neutron powder diffraction, electron diffraction, and high-resolution transmission electron microscopy reveal the structure to be related to VNb9O24.9-type phases, however, with severe disorder hampering full structure determination. Still, the results demonstrate the possibility of a future synthesis of the potential binary oxide Mo2O5. On the basis of these findings, a tentative suggestion on the crystal structure of the potential compound Mo2O5, backed by electronic-structure and phonon calculations from first principles, is given." @default.
- W2735758330 created "2017-07-21" @default.
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- W2735758330 date "2017-07-17" @default.
- W2735758330 modified "2023-10-09" @default.
- W2735758330 title "Molybdenum Oxide Nitrides of the Mo2(O,N,□)5 Type: On the Way to Mo2O5" @default.
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- W2735758330 doi "https://doi.org/10.1021/acs.inorgchem.7b00551" @default.