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- W2736013387 abstract "A cyanide-free one-pot procedure was developed to access 2-amino-3-hydroxy-3H-indoles, which involved: (1) in situ formation of ketenimines by the reaction of N′-(1-(2-aminophenyl)ethylidene)-p-tosylhydrazones with isonitriles; (2) the intramolecular nucleophilic attack of ketenimines by the amino in phenyl furnishing the ring closure leading to 2-aminoindoles; (3) the oxidation of 2-aminoindoles by O2 leading to 2-amino-3-hydroxy-3H-indoles. This strategy represents not only a key compliment to the sporadic synthetic methods toward 2-amino-3-hydroxy-3H-indoles but also progress in N-tosylhydrazone, isonitrile, and ketenimine chemistry." @default.
- W2736013387 created "2017-07-21" @default.
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- W2736013387 date "2017-07-25" @default.
- W2736013387 modified "2023-10-18" @default.
- W2736013387 title "Synthesis of 2-Amino-3-hydroxy-3<i>H</i>-indoles via Palladium-Catalyzed One-Pot Reaction of Isonitriles, Oxygen, and <i>N</i>-Tosylhydrazones Derived from 2-Acylanilines" @default.
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- W2736013387 doi "https://doi.org/10.1021/acs.joc.7b01195" @default.
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