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- W2736355763 abstract "An investigation has been conducted in order to gain information on the defect structure of SrO in the temperature range 600°C ⩽ T⩽ 1400°C and oxygen pressure range 10−12 atm ⩽P02⩽1 atm. The problems of investigating this system in the high oxygen pressure regions have been discussed. Measurements have been reported including phase equilibria, lattice parameter, electrical conductivity, thermoelectric power and thermogravimetric analysis of the SrO System. No new oxide phases of strontium were discovered in the temperature and pressure ranges investigated. The lattice parameter of SrO was found to be constant at 5·1600 ±0·0005 Å within the given temperature and pressure ranges, although larger lattice parameter values were observed in the strontium excess region. A tentative defect model has been proposed which postulates that Frenkel disorder on the anion sublattice predominates. The enthalpy of formation of negatively charged oxygen interstitials and holes as given by the reaction 12O2(g) = O′ + h + (H0+ H1) is found to be (H0+ H1) = 2·0 eV. The enthalpy of formation of negatively charged oxygen interstitials and holes as given by the reaction ø = O′i + V′0+H′F is H′F= 3·0 eV. The oxygen interstitials were found to be highly mobile with diffusivity of 2·4 × 10−5 cm2/sec at 1300°C and an enthalpy of motion of Hm = 0·6 eV." @default.
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- W2736355763 date "1968-02-01" @default.
- W2736355763 modified "2023-09-27" @default.
- W2736355763 title "Studies on the defect structure of strontium oxide" @default.
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- W2736355763 doi "https://doi.org/10.1016/0022-3697(68)90076-0" @default.
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