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- W2736364872 abstract "Abstract A Rhodamine B based dual-response sensor was developed for the independent sensitive and selective fluorescence sensing of Pb 2+ and Al 3+ . Initially, TQ1 exhibited one major fluorescence emission peak centered at 461 nm in ethanol/HEPES solution (1/5, pH 7.4), where HEPES was 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid. After the addition of Pb 2+ , an obvious red shift of 55 nm in fluorescence emission can be clearly observed, accompanied by a fluorescence color conversion, from bluish violet to greenish yellow under 365 UV light. As for Al 3+ , the fluorescence emission of TQ1 experienced a much more remarkable red shift of 124 nm, and its fluorescence color also changed to red. Furthermore, the fluorescence sensing process of Pb 2+ and Al 3+ were completely independent and free from interference of each other via changing the buffer concentration. Detection limit of the probe TQ1 towards Pb 2+ and Al 3+ were 8.3590 × 10 −7 M (linear range 1.6–10.0 μM) and 1.0568 × 10 −8 M (linear range 1.0–10.0 μM) respectively. The complexation properties of TQ1 toward Pb 2+ and Al 3+ were studied in detail." @default.
- W2736364872 created "2017-07-31" @default.
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- W2736364872 date "2018-01-01" @default.
- W2736364872 modified "2023-10-01" @default.
- W2736364872 title "Dual sensitive and selective sensor for Pb2+ and Al3+ with distinctive fluorescence response" @default.
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- W2736364872 doi "https://doi.org/10.1016/j.snb.2017.07.114" @default.
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