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• W2736392916 abstract "Two sesquiterpenes, 4-epi-microsphaeropsisin (1) and a dihydrofurano-2(1H)-naphthalenone (variabilone, 2) which represents a new skeleton, were isolated from endophytic fungus Paraconiothyrium variabile. Reactivity studies showed that eremophilane 1 is a precursor of 2 through acid-promoted methyl 1,2-migration and aromatization. An electrophilic intermediate of this transformation was intercepted by N-acetylcysteamine, a biomimetic nucleophile. Only compound 2 was antibacterial against endophytic bacterium Bacillus subtilis (coisolated with P. variabile), suggesting a role in the microbial competition in plants." @default.
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• W2736392916 date "2017-07-24" @default.
• W2736392916 modified "2023-10-17" @default.
• W2736392916 title "A Reactive Eremophilane and Its Antibacterial 2(1<i>H</i>)-Naphthalenone Rearrangement Product, Witnesses of a Microbial Chemical Warfare" @default.
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• W2736392916 doi "https://doi.org/10.1021/acs.orglett.7b01788" @default.
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