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- W2736401797 abstract "Abstract The study of temperature dependent thermodynamic parameters; Gibb’s free energy difference (ΔG), entropy difference (ΔS) and enthalpy difference (ΔH) between the undercooled liquid and the corresponding equilibrium solid phases has been proved to be extremely advantageous in the study of the thermodynamic behaviour of Metallic glass (MG) forming melts. In last two decades, Au- and Mg-based alloys were found to form glass phases. In present study, the three thermodynamic parameters viz., ΔG, ΔS and ΔH are calculated theoretically in the entire temperature range T m (melting temperature) to T g (glass transition temperature) for both Au- and Mg-based five samples of MGs; Au 77 Ge 13.6 Si 9.4 , Au 53.2 Pb 27.5 Sb 19.3 , Au 81.4 Si 18.6 , Mg 85.5 Cu 14.5 and Mg 81.6 Ga 18.4 on the basis of Taylor’s series expansion. A relative study is also made between the present result and the result obtained experimentally as well as on the basis of expressions projected by the earlier researchers. An attempt is also been made to narrate the reduced glass transition temperature with glass forming ability for all five MGs." @default.
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- W2736401797 date "2017-10-01" @default.
- W2736401797 modified "2023-09-25" @default.
- W2736401797 title "Estimation of thermodynamic parameters for Au- and Mg-based metallic glasses" @default.
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- W2736401797 doi "https://doi.org/10.1016/j.cplett.2017.07.060" @default.
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