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- W2736515232 abstract "A novel kind of low migration one-component Type II photoinitiators was synthesized by Schiff base reaction of thioxanthone aldehyde and amine functional poly(propylene oxide) (PPO) precursors with two different molecular weights. The final initiators (TX-PPO) were characterized in detail by spectral analysis and DFT theoretical calculations. The molecular weight of the PPO directly effects the solubility of the initiator in monomers. The one-component photoinitiating nature of the initiators was demonstrated by photobleaching and photo polymerization of several vinyl monomers in the absence of a hydrogen donor such as triethylamine. Leaching studies on the photocured polymer films show only negligible migration of the photoinitiator." @default.
- W2736515232 created "2017-07-31" @default.
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- W2736515232 date "2017-10-01" @default.
- W2736515232 modified "2023-10-17" @default.
- W2736515232 title "Poly(propylene oxide)-thioxanthone as one-component Type II polymeric photoinitiator for free radical polymerization with low migration behavior" @default.
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- W2736515232 doi "https://doi.org/10.1016/j.eurpolymj.2017.07.030" @default.
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