FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2736545116> ?p ?o ?g. }

• W2736545116 endingPage "3406" @default.
• W2736545116 startingPage "3394" @default.
• W2736545116 abstract "There have been significant developments in the area of perfluoroalkyl group transfer using silicon reagents, specifically in nucleo­philic trifluoromethylation. The mild and versatile activation conditions bestow significant synthetic prowess to the silicon reagents in the area of fluoroalkylations. Owing to the importance of difluoromethylene (CF2) containing compounds in pharmaceuticals, materials, and agrochemicals, several CF2 group transfer methods using related silicon reagents have been developed and studied in detail. This review summarizes the recent developments and trends in this area. 1 Introduction 2 Trimethyl(trifluoromethyl)silane (Me3SiCF3) 3 (Difluoromethyl)trimethylsilane (Me3SiCF2H) 3.1 Nucleophilic Addition 3.2 Nucleophilic Substitution 3.3 Nucleophilic Difluoromethylation of Electron-Deficient Hetero­cycles 3.4 Metal-Mediated Cross Coupling 3.5 Oxidative Coupling of Terminal Alkynes 4 Post-functionalizable Difluoromethyl Transfer Reagents 4.1 (Chlorodifluoromethyl)trimethylsilane (Me3SiCF2Cl) 4.2 (Bromodifluoromethyl)trimethylsilane (Me3SiCF2Br) 4.3 [Difluoro(iodo)methyl]trimethylsilane (Me3SiCF2I) 4.4 [Difluoro(phenylthio)methyl]trimethylsilane (Me3SiCF2SPh) 4.5 [Difluoro(phenylsulfonyl)methyl]trimethylsilane (Me3SiCF2SO2Ph) 4.6 Diethyl [Difluoro(trimethylsilyl)methyl]phosphonate [Me3SiCF2P(O)(OEt)2] 4.7 Ethyl Difluoro(trimethylsilyl)acetate (Me3SiCF2CO2Et) 4.8 Difluoro(trimethylsilyl)acetamides (Me3SiCF2CONR2) 4.9 Difluoro(trimethylsilyl)acetonitrile (Me3SiCF2CN) 5 Others 6 Conclusions" @default.
• W2736545116 created "2017-07-31" @default.
• W2736545116 creator A5047158225 @default.
• W2736545116 creator A5079269161 @default.
• W2736545116 date "2017-07-17" @default.
• W2736545116 modified "2023-10-10" @default.
• W2736545116 title "Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions" @default.
• W2736545116 cites W1188113683 @default.
• W2736545116 cites W1840584400 @default.
• W2736545116 cites W1964186202 @default.
• W2736545116 cites W1971000513 @default.
• W2736545116 cites W1971460754 @default.
• W2736545116 cites W1973215912 @default.
• W2736545116 cites W1983871665 @default.
• W2736545116 cites W1986400227 @default.
• W2736545116 cites W1989005788 @default.
• W2736545116 cites W1991246969 @default.
• W2736545116 cites W1992711945 @default.
• W2736545116 cites W2001602165 @default.
• W2736545116 cites W2015443088 @default.
• W2736545116 cites W2016848221 @default.
• W2736545116 cites W2019803276 @default.
• W2736545116 cites W2025085392 @default.
• W2736545116 cites W2028409357 @default.
• W2736545116 cites W2041980233 @default.
• W2736545116 cites W2045380964 @default.
• W2736545116 cites W2052243561 @default.
• W2736545116 cites W2054850774 @default.
• W2736545116 cites W2058346743 @default.
• W2736545116 cites W2067630627 @default.
• W2736545116 cites W2070886586 @default.
• W2736545116 cites W2084546812 @default.
• W2736545116 cites W2091440745 @default.
• W2736545116 cites W2096302098 @default.
• W2736545116 cites W2105734453 @default.
• W2736545116 cites W2107530855 @default.
• W2736545116 cites W2110939537 @default.
• W2736545116 cites W2112054856 @default.
• W2736545116 cites W2123203611 @default.
• W2736545116 cites W2129641972 @default.
• W2736545116 cites W2141471401 @default.
• W2736545116 cites W2167680317 @default.
• W2736545116 cites W2169769457 @default.
• W2736545116 cites W2179070715 @default.
• W2736545116 cites W2199899818 @default.
• W2736545116 cites W2201119188 @default.
• W2736545116 cites W2220799673 @default.
• W2736545116 cites W2234811979 @default.
• W2736545116 cites W2274711197 @default.
• W2736545116 cites W2293437745 @default.
• W2736545116 cites W2293762236 @default.
• W2736545116 cites W2298217989 @default.
• W2736545116 cites W2319245444 @default.
• W2736545116 cites W2319670228 @default.
• W2736545116 cites W2320468775 @default.
• W2736545116 cites W2321124323 @default.
• W2736545116 cites W2326317757 @default.
• W2736545116 cites W2327722507 @default.
• W2736545116 cites W2330459373 @default.
• W2736545116 cites W2331132238 @default.
• W2736545116 cites W2333129245 @default.
• W2736545116 cites W2334848778 @default.
• W2736545116 cites W2344637366 @default.
• W2736545116 cites W2417951554 @default.
• W2736545116 cites W2462671140 @default.
• W2736545116 cites W2465955495 @default.
• W2736545116 cites W2473110305 @default.
• W2736545116 cites W2518283814 @default.
• W2736545116 cites W2518435190 @default.
• W2736545116 cites W2519510490 @default.
• W2736545116 cites W2587533365 @default.
• W2736545116 cites W2588771322 @default.
• W2736545116 cites W2597662229 @default.
• W2736545116 cites W2603852585 @default.
• W2736545116 cites W2607166321 @default.
• W2736545116 cites W285821682 @default.
• W2736545116 cites W2949430564 @default.
• W2736545116 cites W2949624222 @default.
• W2736545116 cites W2949639686 @default.
• W2736545116 cites W2949851654 @default.
• W2736545116 cites W2950037832 @default.
• W2736545116 cites W2952945966 @default.
• W2736545116 cites W2953341825 @default.
• W2736545116 cites W411683072 @default.
• W2736545116 cites W644423412 @default.
• W2736545116 cites W839169393 @default.
• W2736545116 doi "https://doi.org/10.1055/s-0036-1588489" @default.
• W2736545116 hasPublicationYear "2017" @default.
• W2736545116 type Work @default.
• W2736545116 sameAs 2736545116 @default.
• W2736545116 citedByCount "58" @default.
• W2736545116 countsByYear W27365451162017 @default.
• W2736545116 countsByYear W27365451162018 @default.
• W2736545116 countsByYear W27365451162019 @default.
• W2736545116 countsByYear W27365451162020 @default.
• W2736545116 countsByYear W27365451162021 @default.
• W2736545116 countsByYear W27365451162022 @default.
• W2736545116 countsByYear W27365451162023 @default.

• next