Matches in SemOpenAlex for { <https://semopenalex.org/work/W2736550343> ?p ?o ?g. }
- W2736550343 endingPage "894" @default.
- W2736550343 startingPage "886" @default.
- W2736550343 abstract "Inspired by the ability of the sea cucumber to (reversibly) increase the stiffness of its dermis upon exposure to a stimulus, we herein report a stimuli-responsive nanocomposite that can reversibly increase its stiffness upon exposure to warm water. Nanocomposites composed of cellulose nanocrystals (CNCs) that are grafted with a lower critical solution temperature (LCST) polymer embedded within a poly(vinyl acetate) (PVAc) matrix show a dramatic increase in modulus, for example, from 1 to 350 MPa upon exposure to warm water, the hypothesis being that grafting the polymers from the CNCs disrupts the interactions between the nanofibers and minimizes the mechanical reinforcement of the film. However, exposure to water above the LCST leads to the collapse of the polymer chains and subsequent stiffening of the nanocomposite as a result of the enhanced CNC interactions. Backing up this hypothesis are energy conserving dissipative particle dynamics (EDPD) simulations which show that the attractive interactions between CNCs are switched on upon the temperature-induced collapse of the grafted polymer chains, resulting in the formation of a percolating reinforcing network." @default.
- W2736550343 created "2017-07-31" @default.
- W2736550343 creator A5021801211 @default.
- W2736550343 creator A5027202027 @default.
- W2736550343 creator A5033181220 @default.
- W2736550343 creator A5056508088 @default.
- W2736550343 creator A5058571119 @default.
- W2736550343 creator A5075335199 @default.
- W2736550343 date "2017-07-26" @default.
- W2736550343 modified "2023-10-16" @default.
- W2736550343 title "Biomimetic Reversible Heat-Stiffening Polymer Nanocomposites" @default.
- W2736550343 cites W1106846113 @default.
- W2736550343 cites W1922087524 @default.
- W2736550343 cites W1965701240 @default.
- W2736550343 cites W1975723722 @default.
- W2736550343 cites W1976048030 @default.
- W2736550343 cites W1992921901 @default.
- W2736550343 cites W1995586409 @default.
- W2736550343 cites W1996472287 @default.
- W2736550343 cites W2008151211 @default.
- W2736550343 cites W2018283074 @default.
- W2736550343 cites W2026630139 @default.
- W2736550343 cites W2027447145 @default.
- W2736550343 cites W2028186092 @default.
- W2736550343 cites W2032941259 @default.
- W2736550343 cites W2043958321 @default.
- W2736550343 cites W2045022361 @default.
- W2736550343 cites W2050186721 @default.
- W2736550343 cites W2059414533 @default.
- W2736550343 cites W2077474285 @default.
- W2736550343 cites W2091634857 @default.
- W2736550343 cites W2093310284 @default.
- W2736550343 cites W2101642953 @default.
- W2736550343 cites W2109520483 @default.
- W2736550343 cites W2109558113 @default.
- W2736550343 cites W2132131875 @default.
- W2736550343 cites W2132823001 @default.
- W2736550343 cites W2135499842 @default.
- W2736550343 cites W2139926893 @default.
- W2736550343 cites W2140799895 @default.
- W2736550343 cites W2147393041 @default.
- W2736550343 cites W2314368960 @default.
- W2736550343 cites W2316506543 @default.
- W2736550343 cites W2317033406 @default.
- W2736550343 cites W2321293646 @default.
- W2736550343 cites W2322085264 @default.
- W2736550343 cites W2326393292 @default.
- W2736550343 cites W2327446752 @default.
- W2736550343 cites W2328208821 @default.
- W2736550343 cites W2481546675 @default.
- W2736550343 cites W2513488291 @default.
- W2736550343 cites W2547744111 @default.
- W2736550343 cites W3149377315 @default.
- W2736550343 cites W4244569713 @default.
- W2736550343 cites W4298444352 @default.
- W2736550343 doi "https://doi.org/10.1021/acscentsci.7b00215" @default.
- W2736550343 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5571458" @default.
- W2736550343 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28852703" @default.
- W2736550343 hasPublicationYear "2017" @default.
- W2736550343 type Work @default.
- W2736550343 sameAs 2736550343 @default.
- W2736550343 citedByCount "57" @default.
- W2736550343 countsByYear W27365503432017 @default.
- W2736550343 countsByYear W27365503432018 @default.
- W2736550343 countsByYear W27365503432019 @default.
- W2736550343 countsByYear W27365503432020 @default.
- W2736550343 countsByYear W27365503432021 @default.
- W2736550343 countsByYear W27365503432022 @default.
- W2736550343 countsByYear W27365503432023 @default.
- W2736550343 crossrefType "journal-article" @default.
- W2736550343 hasAuthorship W2736550343A5021801211 @default.
- W2736550343 hasAuthorship W2736550343A5027202027 @default.
- W2736550343 hasAuthorship W2736550343A5033181220 @default.
- W2736550343 hasAuthorship W2736550343A5056508088 @default.
- W2736550343 hasAuthorship W2736550343A5058571119 @default.
- W2736550343 hasAuthorship W2736550343A5075335199 @default.
- W2736550343 hasBestOaLocation W27365503431 @default.
- W2736550343 hasConcept C108729823 @default.
- W2736550343 hasConcept C127413603 @default.
- W2736550343 hasConcept C15920480 @default.
- W2736550343 hasConcept C159985019 @default.
- W2736550343 hasConcept C188027245 @default.
- W2736550343 hasConcept C188109995 @default.
- W2736550343 hasConcept C192562407 @default.
- W2736550343 hasConcept C2779372316 @default.
- W2736550343 hasConcept C3231350 @default.
- W2736550343 hasConcept C42360764 @default.
- W2736550343 hasConcept C45594756 @default.
- W2736550343 hasConcept C521977710 @default.
- W2736550343 hasConcept C92880739 @default.
- W2736550343 hasConceptScore W2736550343C108729823 @default.
- W2736550343 hasConceptScore W2736550343C127413603 @default.
- W2736550343 hasConceptScore W2736550343C15920480 @default.
- W2736550343 hasConceptScore W2736550343C159985019 @default.
- W2736550343 hasConceptScore W2736550343C188027245 @default.
- W2736550343 hasConceptScore W2736550343C188109995 @default.
- W2736550343 hasConceptScore W2736550343C192562407 @default.
- W2736550343 hasConceptScore W2736550343C2779372316 @default.