Matches in SemOpenAlex for { <https://semopenalex.org/work/W2736581657> ?p ?o ?g. }
- W2736581657 endingPage "603" @default.
- W2736581657 startingPage "597" @default.
- W2736581657 abstract "The electrochemistry of dppm-bridged dithiolate complexes [M2(CO)4(μ-dppm){μ-S(CH2) n S}] (M = Fe, Ru; n = 2, 3) has been studied by cyclic voltammetry. The diiron complexes show similar electrochemical responses in CH2Cl2 but differ significantly in MeCN, while the diruthenium complexes change only slightly with changes in the dithiolate backbone and solvent. Proton-reduction studies in MeCN with HBF4·Et2O as the proton source show that all are active catalysts for proton reduction in their singly reduced state. An additional catalytic event is observed for all, resulting from their partial protonation giving [M2(CO)4(μ-dppm){μ-S(CH2) n S}(μ-H)][BF4]. The diiron complexes show better long-term stability to acids, the diruthenium complexes degrading at high acid concentrations. The electrochemical response of dithiolate complexes [M2(CO)4(μ-dppm){μ-S(CH2) n S}] (M = Fe, Ru; n = 2, 3) has been investigated in different solvents as well as they have been tested as electrocatalysts for the reduction of protons to hydrogen." @default.
- W2736581657 created "2017-07-31" @default.
- W2736581657 creator A5016503049 @default.
- W2736581657 creator A5036461859 @default.
- W2736581657 creator A5059773332 @default.
- W2736581657 date "2017-07-24" @default.
- W2736581657 modified "2023-10-03" @default.
- W2736581657 title "A comparative study of the electrochemical and proton-reduction behaviour of diphosphine-dithiolate complexes [M2(CO)4(μ-dppm){μ-S(CH2) n S}] (M = Fe, Ru; n = 2, 3)" @default.
- W2736581657 cites W1829575213 @default.
- W2736581657 cites W1862448473 @default.
- W2736581657 cites W1964433007 @default.
- W2736581657 cites W1965056630 @default.
- W2736581657 cites W1968162464 @default.
- W2736581657 cites W1977101738 @default.
- W2736581657 cites W1984278749 @default.
- W2736581657 cites W1987969019 @default.
- W2736581657 cites W1989119939 @default.
- W2736581657 cites W1989211000 @default.
- W2736581657 cites W1990130563 @default.
- W2736581657 cites W1990634487 @default.
- W2736581657 cites W1995586452 @default.
- W2736581657 cites W2005285870 @default.
- W2736581657 cites W2008666852 @default.
- W2736581657 cites W2013046539 @default.
- W2736581657 cites W2014141708 @default.
- W2736581657 cites W2021954807 @default.
- W2736581657 cites W2022113368 @default.
- W2736581657 cites W2024137021 @default.
- W2736581657 cites W2026598559 @default.
- W2736581657 cites W2027245757 @default.
- W2736581657 cites W2036780929 @default.
- W2736581657 cites W2038732926 @default.
- W2736581657 cites W2041298522 @default.
- W2736581657 cites W2041864511 @default.
- W2736581657 cites W2046316485 @default.
- W2736581657 cites W2047560937 @default.
- W2736581657 cites W2050334066 @default.
- W2736581657 cites W2055342637 @default.
- W2736581657 cites W2063448276 @default.
- W2736581657 cites W2065028124 @default.
- W2736581657 cites W2068453999 @default.
- W2736581657 cites W2068718415 @default.
- W2736581657 cites W2069119864 @default.
- W2736581657 cites W2069234568 @default.
- W2736581657 cites W2073508479 @default.
- W2736581657 cites W2077845926 @default.
- W2736581657 cites W2079672871 @default.
- W2736581657 cites W2080075262 @default.
- W2736581657 cites W2084128687 @default.
- W2736581657 cites W2093405925 @default.
- W2736581657 cites W2093515242 @default.
- W2736581657 cites W2093604798 @default.
- W2736581657 cites W2102501346 @default.
- W2736581657 cites W2104774802 @default.
- W2736581657 cites W2137932444 @default.
- W2736581657 cites W2144468862 @default.
- W2736581657 cites W2167323648 @default.
- W2736581657 cites W2292062105 @default.
- W2736581657 cites W2313863146 @default.
- W2736581657 cites W2316069400 @default.
- W2736581657 cites W2331668115 @default.
- W2736581657 cites W2334251352 @default.
- W2736581657 cites W2386607147 @default.
- W2736581657 cites W2531143943 @default.
- W2736581657 cites W2604090098 @default.
- W2736581657 doi "https://doi.org/10.1007/s11243-017-0164-6" @default.
- W2736581657 hasPublicationYear "2017" @default.
- W2736581657 type Work @default.
- W2736581657 sameAs 2736581657 @default.
- W2736581657 citedByCount "10" @default.
- W2736581657 countsByYear W27365816572018 @default.
- W2736581657 countsByYear W27365816572019 @default.
- W2736581657 countsByYear W27365816572020 @default.
- W2736581657 countsByYear W27365816572022 @default.
- W2736581657 countsByYear W27365816572023 @default.
- W2736581657 crossrefType "journal-article" @default.
- W2736581657 hasAuthorship W2736581657A5016503049 @default.
- W2736581657 hasAuthorship W2736581657A5036461859 @default.
- W2736581657 hasAuthorship W2736581657A5059773332 @default.
- W2736581657 hasBestOaLocation W27365816571 @default.
- W2736581657 hasConcept C121332964 @default.
- W2736581657 hasConcept C145148216 @default.
- W2736581657 hasConcept C147789679 @default.
- W2736581657 hasConcept C155647269 @default.
- W2736581657 hasConcept C161790260 @default.
- W2736581657 hasConcept C17525397 @default.
- W2736581657 hasConcept C178790620 @default.
- W2736581657 hasConcept C179104552 @default.
- W2736581657 hasConcept C185592680 @default.
- W2736581657 hasConcept C2777463227 @default.
- W2736581657 hasConcept C2777869211 @default.
- W2736581657 hasConcept C2780471494 @default.
- W2736581657 hasConcept C30095370 @default.
- W2736581657 hasConcept C514695523 @default.
- W2736581657 hasConcept C52859227 @default.
- W2736581657 hasConcept C54516573 @default.
- W2736581657 hasConcept C55904794 @default.
- W2736581657 hasConcept C62520636 @default.