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- W2736680843 abstract "In search of new fully fluorinated ligands which effectively sensitized the lanthanide luminescence the 4,5,6,7-tetrafluoro-1,3-benzothiazol-2(3Н)-thione (HmbtF) was proposed. Based on this ligand a set of new complexes LnL3(THF)2 (Ln1) (Ln = Nd, Gd, Tb, Dy, Er, Yb) was synthesized and their luminescence were studied. The structure of the compounds was established with an example of Gd derivative. The triplet state energy of mbtF was found to be 21500 cm−1 that enables the resonant energy transfer to Dy3+, Tb3+, Nd3+ and Er3+ ions and stipulates metal-centered emission of some complexes. In case of Yb1 the observed luminescence of Yb3+ ion probably occurs due to the non-resonant energy transfer." @default.
- W2736680843 created "2017-07-31" @default.
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- W2736680843 date "2017-11-01" @default.
- W2736680843 modified "2023-10-01" @default.
- W2736680843 title "Fluorinated mercaptobenzothiazolates of lanthanides: Synthesis, structure and photoluminescence" @default.
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- W2736680843 doi "https://doi.org/10.1016/j.molstruc.2017.07.035" @default.
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