FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2736686656> ?p ?o ?g. }

• W2736686656 endingPage "9222" @default.
• W2736686656 startingPage "9213" @default.
• W2736686656 abstract "Subsurface upgrading of heavy oil via solvent deasphalting has been reported previously under laboratory and field conditions. However, these processes require a relatively high solvent-to-oil ratio (SvOR > 1:1 v/v) to induce subsurface asphaltene precipitation, increase oil production, and upgrade crude oil in situ. In our previous work, lab experiments demonstrated that asphaltene precipitants reduce the SvOR (∼30–50 vol %) for subsurface upgrading at initial reservoir conditions and when heat is also applied. In this work, the preparative separations were carried out using benzoyl peroxide (BP), Fe2O3, and NiO nanoparticles as asphaltene precipitants for Venezuelan and Canadian heavy crude oils. Initial experiments showed that BP is the most effective additive, producing an increase of ∼21 wt % in the asphaltene content for a 2500 mg/kg dosage. Preparative separations at 5:1 vol/wt ratio and 50 °C showed that the order of activity as asphaltene precipitants is BP > NiO > Fe2O3. In the presence of nickel- and iron-containing precipitants, most of these metals are found in the asphaltenes indicating that the nanoparticles are acting as nucleation sites. Spectroscopic and mechanistic studies using BP as precipitant suggest a free radical mechanism that involves the thermally initiated homolytic cleavage of BP, follow by abstraction of a hydrogen atom from the asphaltenes or maltenes to produce free radical species. In the termination steps, the latter species react with each other to generate new asphaltene species that are not present in the original crude oils." @default.
• W2736686656 created "2017-07-31" @default.
• W2736686656 creator A5016987817 @default.
• W2736686656 creator A5017702204 @default.
• W2736686656 creator A5017786320 @default.
• W2736686656 creator A5019399289 @default.
• W2736686656 creator A5032888457 @default.
• W2736686656 creator A5047228649 @default.
• W2736686656 creator A5056035633 @default.
• W2736686656 creator A5090137389 @default.
• W2736686656 date "2017-08-10" @default.
• W2736686656 modified "2023-10-01" @default.
• W2736686656 title "Subsurface Upgrading of Heavy Oils via Solvent Deasphalting Using Asphaltene Precipitants. Preparative Separations and Mechanism of Asphaltene Precipitation Using Benzoyl Peroxide as Precipitant" @default.
• W2736686656 cites W1203413285 @default.
• W2736686656 cites W1976407350 @default.
• W2736686656 cites W1979547790 @default.
• W2736686656 cites W1999177791 @default.
• W2736686656 cites W1999933707 @default.
• W2736686656 cites W2007015755 @default.
• W2736686656 cites W2009541154 @default.
• W2736686656 cites W2011071620 @default.
• W2736686656 cites W2027883013 @default.
• W2736686656 cites W2030842891 @default.
• W2736686656 cites W2036260803 @default.
• W2736686656 cites W2041643203 @default.
• W2736686656 cites W2045832756 @default.
• W2736686656 cites W2047173477 @default.
• W2736686656 cites W2049059703 @default.
• W2736686656 cites W2059525970 @default.
• W2736686656 cites W2069459653 @default.
• W2736686656 cites W2072595982 @default.
• W2736686656 cites W2073889573 @default.
• W2736686656 cites W2074786424 @default.
• W2736686656 cites W2079288302 @default.
• W2736686656 cites W2090793515 @default.
• W2736686656 cites W2092333094 @default.
• W2736686656 cites W2144692323 @default.
• W2736686656 cites W2329664456 @default.
• W2736686656 cites W2414064304 @default.
• W2736686656 cites W2485351879 @default.
• W2736686656 cites W2516056908 @default.
• W2736686656 cites W2516073015 @default.
• W2736686656 cites W4238723144 @default.
• W2736686656 doi "https://doi.org/10.1021/acs.energyfuels.7b01588" @default.
• W2736686656 hasPublicationYear "2017" @default.
• W2736686656 type Work @default.
• W2736686656 sameAs 2736686656 @default.
• W2736686656 citedByCount "7" @default.
• W2736686656 countsByYear W27366866562019 @default.
• W2736686656 countsByYear W27366866562020 @default.
• W2736686656 countsByYear W27366866562022 @default.
• W2736686656 countsByYear W27366866562023 @default.
• W2736686656 crossrefType "journal-article" @default.
• W2736686656 hasAuthorship W2736686656A5016987817 @default.
• W2736686656 hasAuthorship W2736686656A5017702204 @default.
• W2736686656 hasAuthorship W2736686656A5017786320 @default.
• W2736686656 hasAuthorship W2736686656A5019399289 @default.
• W2736686656 hasAuthorship W2736686656A5032888457 @default.
• W2736686656 hasAuthorship W2736686656A5047228649 @default.
• W2736686656 hasAuthorship W2736686656A5056035633 @default.
• W2736686656 hasAuthorship W2736686656A5090137389 @default.
• W2736686656 hasConcept C107054158 @default.
• W2736686656 hasConcept C121332964 @default.
• W2736686656 hasConcept C127413603 @default.
• W2736686656 hasConcept C153294291 @default.
• W2736686656 hasConcept C178790620 @default.
• W2736686656 hasConcept C179104552 @default.
• W2736686656 hasConcept C185592680 @default.
• W2736686656 hasConcept C2778885487 @default.
• W2736686656 hasConcept C2780471494 @default.
• W2736686656 hasConcept C42360764 @default.
• W2736686656 hasConcept C44228677 @default.
• W2736686656 hasConcept C504270822 @default.
• W2736686656 hasConcept C521977710 @default.
• W2736686656 hasConcept C533411734 @default.
• W2736686656 hasConcept C65324659 @default.
• W2736686656 hasConceptScore W2736686656C107054158 @default.
• W2736686656 hasConceptScore W2736686656C121332964 @default.
• W2736686656 hasConceptScore W2736686656C127413603 @default.
• W2736686656 hasConceptScore W2736686656C153294291 @default.
• W2736686656 hasConceptScore W2736686656C178790620 @default.
• W2736686656 hasConceptScore W2736686656C179104552 @default.
• W2736686656 hasConceptScore W2736686656C185592680 @default.
• W2736686656 hasConceptScore W2736686656C2778885487 @default.
• W2736686656 hasConceptScore W2736686656C2780471494 @default.
• W2736686656 hasConceptScore W2736686656C42360764 @default.
• W2736686656 hasConceptScore W2736686656C44228677 @default.
• W2736686656 hasConceptScore W2736686656C504270822 @default.
• W2736686656 hasConceptScore W2736686656C521977710 @default.
• W2736686656 hasConceptScore W2736686656C533411734 @default.
• W2736686656 hasConceptScore W2736686656C65324659 @default.
• W2736686656 hasFunder F4320310537 @default.
• W2736686656 hasIssue "9" @default.
• W2736686656 hasLocation W27366866561 @default.
• W2736686656 hasOpenAccess W2736686656 @default.
• W2736686656 hasPrimaryLocation W27366866561 @default.
• W2736686656 hasRelatedWork W1971372227 @default.
• W2736686656 hasRelatedWork W1985147233 @default.

• next