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- W2736842368 abstract "It is shown that at least two —and in some cases three—lattice sites are involved in the formation of thermal defects in CsCl structures. Significant defect mixing can be expected to occur at higher temperatures. The experimental determination of defect formation energy based on the tacit assumption of monovacancy formation is therefore expected to result in erroneously low values. The effects to be expected from the variation of composition within the stability range of the compound are discussed. It is shown that the effect of the defect mixing may lead to anomalous melting behavior in the vicinity of the stoichiometric composition. The significance of the relative values of the different defect formation energies is briefly discussed for compounds ranging from purely ionic to fully disordered. It is concluded that similar considerations apply to other intermetallic compounds, regardless of structure, in which an extensive range of structure stability exists." @default.
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- W2736842368 date "1968-01-01" @default.
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- W2736842368 title "Structure defects in CsCl intermetallic compounds—I. Theory" @default.
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- W2736842368 doi "https://doi.org/10.1016/0022-3697(68)90252-7" @default.
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