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- W2737004035 abstract "K-absorption edges and associated extended fine structure is recorded for zinc and zinc chalcogenides using a 40 cm, automatic scanning, Cauchois type X-ray spectrometer. It is observed that there is a correlation between the positive X-ray K-absorption edge chemical shift and Phillips' electronegativity difference C for zinc chalcogenides. The bond lengths for these compounds are determined using Lytle, Chivate et al. and Levy's methods. These bond lengths are observed to tally well with X-ray crystallographic data. The covalent energy gaps in Phillips' theory are determined using bond lengths determined by Chivate et al.'s method. Values of ionicities are obtained from X-ray spectroscopically determined values of C and Eh and are compared with Phillips' spectroscopically determined ionicities for zinc chalcogenides. It is shown that X-ray spectroscopically determined values of ionicities for these compounds show a more correct chemical trend." @default.
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- W2737004035 date "1976-01-01" @default.
- W2737004035 modified "2023-10-16" @default.
- W2737004035 title "Determination of ionicity in zinc chalcogenides by X-ray absorption study" @default.
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- W2737004035 doi "https://doi.org/10.1016/0022-3697(76)90127-x" @default.
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