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• W2737074345 abstract "The frustrated Lewis pair (FLP) comprised of B(C6F5)3 and 1,2,2,6,6-pentamethylpiperidine (PMP) can efficiently catalyze Z-selective hydrophosphonylation of terminal ynones with a Z/E selectivity of up to 20 : 1. Mechanistic studies suggest that the trans arrangement of the phosphite nucleophilic attack and hydrogen bond formation on the alkyne moiety is responsible for the observed Z-selectivity." @default.
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• W2737074345 date "2017-01-01" @default.
• W2737074345 modified "2023-10-18" @default.
• W2737074345 title "Activation of the P–H bond by a frustrated Lewis pair and its application in catalytic Z-selective hydrophosphonylation of terminal ynones" @default.
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• W2737074345 doi "https://doi.org/10.1039/c7cc05028c" @default.
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