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• W2737168045 abstract "An experimental and theoretical study on hydrogen-atom transfer dynamics in the hydrogen-bonded substituted phenol/phenoxyl complex of the blue aroxyl (2,4,6-tri-tert-butylphenoxyl) is presented. The experimental exchange dynamics is determined in different organic solvents from the temperature-dependent alternating line-width effect in the continuous-wave ESR spectrum. From bent Arrhenius plots, effective tunnelling contributions with parallel heavy-atom motion are concluded. To clarify the transfer mechanism, reaction paths for different conformers of the substituted phenol/phenoxyl complex are modelled theoretically. Various DFT and post-Hartree-Fock methods including multireference methods are applied. From the comparison of experimental and theoretical data it is concluded that the system favours concerted hydrogen-atom transfer along a parabolic reaction path caused by heavy-atom motion." @default.
• W2737168045 created "2017-07-31" @default.
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• W2737168045 date "2017-08-30" @default.
• W2737168045 modified "2023-09-23" @default.
• W2737168045 title "Insights into the Hydrogen-Atom Transfer of the Blue Aroxyl" @default.
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• W2737168045 doi "https://doi.org/10.1002/cphc.201700603" @default.
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