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- W2737274510 abstract "A synthetic pathway to a functionalized [9]cycloparaphenylene bearing three indeno[2,1-a]fluorene-11,12-dione-2,9-diyl units in the macrocyclic ring structure ([3]CIFO) has been developed. The 1H and 13C NMR spectra show that only the anti rotamer (anti-[3]CIFO) is produced. DFT calculations indicate that the anti rotamer is thermodynamically more stable than the syn rotamer by 4.3 kcal/mol, and the rotational barrier from the anti to syn rotamer is estimated to be 23.3 kcal/mol. The UV–vis and fluorescence spectra and cyclic voltammogram of anti-[3]CIFO were investigated." @default.
- W2737274510 created "2017-07-31" @default.
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- W2737274510 date "2017-07-20" @default.
- W2737274510 modified "2023-10-14" @default.
- W2737274510 title "Synthesis and Structure of a Functionalized [9]Cycloparaphenylene Bearing Three Indeno[2,1-<i>a</i>]fluorene-11,12-dione-2,9-diyl Units" @default.
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- W2737274510 doi "https://doi.org/10.1021/acs.orglett.7b01866" @default.
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