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• W2738008399 abstract "The term ‘chiral’ is defined as “geometrical figure, or group of points whose image in a plane mirror cannot be brought to coincide with itself.” The obvious examples are our hands and foot, as left hand (foot) becomes right hand (foot) in a mirror, and vice-versa. In this paper we shall focus on chirality of molecules particularly in the crystalline state where molecules are densely surrounded by neighbouring molecules in an ordered manner. In the crystalline state, conformational flexibility is restricted, and chiral discrimination energy is order of magnitudes larger compared with that in the solution phase. Thus, facile optical resolution during supramolecular crystallization can be achieved. Further, co-grinding of multiple crystals of different compounds produces unique co-crystals or crystals of unique compounds. We have ascribed the origin of these interesting phenomena to the memory of the original crystal structures which is at least partially retained during the solid-state crystallization processes. These novel chiral crystalline chemistries will be introduced, mainly focused on our own work." @default.
• W2738008399 created "2017-07-31" @default.
• W2738008399 creator A5016093016 @default.
• W2738008399 date "2017-01-01" @default.
• W2738008399 modified "2023-09-27" @default.
• W2738008399 title "Molecular Structure and Chirality and Chiral Crystals" @default.
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• W2738008399 doi "https://doi.org/10.1007/978-94-024-1117-1_2" @default.
• W2738008399 hasPublicationYear "2017" @default.
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