FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2738204425> ?p ?o ?g. }

• W2738204425 abstract "Environmental contextPollution of the aquatic environment by drugs results not only during their manufacture, but also from the excretion of drug residues and the discharge of expired drugs by households and hospitals. The transformation of ciprofloxacin, one of the leading antibiotic drugs, in the presence of surfactants has been investigated. The results provide a better understanding of how ciprofloxacin degrades in aquatic environments by considering the effect of omnipresent surfactants. AbstractThe kinetics of the oxidative transformation, i.e. oxidative degradation, of ciprofloxacin (CIP) by chloramine-T (CAT) in cationic and anionic micelle media during the water chlorination process was studied spectrophotometrically at 275nm and 298K. The influence of added salts (1–10×10–4moldm–3) and solvent polarity of the medium on the reaction was studied. The orders with respect to substrate CIP and oxidant CAT were found to be first order in each. The variation of acid concentrations showed opposite effects in cationic and anionic micellar aggregates. Liquid chromatography–electrospray ionisation mass spectrometry was used to identify degradation products of CIP, which confirmed the full dealkylation of the piperazine ring in CIP as the major product. The piperazine moiety of CIP is the principal active site for the CAT during oxidation. Activation parameters for the CIP degradation in cationic and anionic micelles were evaluated by studying the reaction at different temperatures, which lent further support to the proposed degradation mechanism for CIP. The rate constants were evaluated to confirm the micellar effect from incorporating sodium dodecyl sulfate and cetyltrimethylammonium bromide in the reaction mixture and the intrinsic reactivity constants were determined in the aqueous as well as in the micellar pseudo-phases as 4.85 and 0.0083." @default.
• W2738204425 created "2017-07-31" @default.
• W2738204425 creator A5009557371 @default.
• W2738204425 creator A5012581038 @default.
• W2738204425 creator A5062296541 @default.
• W2738204425 creator A5083253755 @default.
• W2738204425 creator A5087325737 @default.
• W2738204425 date "2017-01-01" @default.
• W2738204425 modified "2023-09-27" @default.
• W2738204425 title "Micellar oxidative transformation of ciprofloxacin: a kinetic investigation" @default.
• W2738204425 cites W1656495745 @default.
• W2738204425 cites W1954536473 @default.
• W2738204425 cites W1965928527 @default.
• W2738204425 cites W1966201742 @default.
• W2738204425 cites W1966842739 @default.
• W2738204425 cites W1968832098 @default.
• W2738204425 cites W1979333678 @default.
• W2738204425 cites W1982614541 @default.
• W2738204425 cites W1985034024 @default.
• W2738204425 cites W1986790014 @default.
• W2738204425 cites W1987672655 @default.
• W2738204425 cites W1993926520 @default.
• W2738204425 cites W1996463190 @default.
• W2738204425 cites W1996925786 @default.
• W2738204425 cites W1997506183 @default.
• W2738204425 cites W2001630149 @default.
• W2738204425 cites W2002155365 @default.
• W2738204425 cites W2004304540 @default.
• W2738204425 cites W2004570347 @default.
• W2738204425 cites W2004856900 @default.
• W2738204425 cites W2011511792 @default.
• W2738204425 cites W2013280569 @default.
• W2738204425 cites W2013616039 @default.
• W2738204425 cites W2013929635 @default.
• W2738204425 cites W2017442478 @default.
• W2738204425 cites W2017968809 @default.
• W2738204425 cites W2021847451 @default.
• W2738204425 cites W2025480249 @default.
• W2738204425 cites W2026532783 @default.
• W2738204425 cites W2028808607 @default.
• W2738204425 cites W2029593210 @default.
• W2738204425 cites W2036733630 @default.
• W2738204425 cites W2040549579 @default.
• W2738204425 cites W2046963769 @default.
• W2738204425 cites W2055975939 @default.
• W2738204425 cites W2056722139 @default.
• W2738204425 cites W2058904075 @default.
• W2738204425 cites W2063799009 @default.
• W2738204425 cites W2066462047 @default.
• W2738204425 cites W2069700993 @default.
• W2738204425 cites W2075212456 @default.
• W2738204425 cites W2075456601 @default.
• W2738204425 cites W2078255868 @default.
• W2738204425 cites W2082060369 @default.
• W2738204425 cites W2085710947 @default.
• W2738204425 cites W2095512453 @default.
• W2738204425 cites W2095945267 @default.
• W2738204425 cites W2097496972 @default.
• W2738204425 cites W2126544699 @default.
• W2738204425 cites W2136178052 @default.
• W2738204425 cites W2151469380 @default.
• W2738204425 cites W2152648579 @default.
• W2738204425 cites W2157324762 @default.
• W2738204425 cites W2191889917 @default.
• W2738204425 cites W2298649681 @default.
• W2738204425 cites W2315565293 @default.
• W2738204425 cites W2321085967 @default.
• W2738204425 cites W2326062080 @default.
• W2738204425 cites W2569960672 @default.
• W2738204425 cites W3004511840 @default.
• W2738204425 cites W2548808169 @default.
• W2738204425 doi "https://doi.org/10.1071/en17034" @default.
• W2738204425 hasPublicationYear "2017" @default.
• W2738204425 type Work @default.
• W2738204425 sameAs 2738204425 @default.
• W2738204425 citedByCount "8" @default.
• W2738204425 countsByYear W27382044252018 @default.
• W2738204425 countsByYear W27382044252019 @default.
• W2738204425 countsByYear W27382044252020 @default.
• W2738204425 crossrefType "journal-article" @default.
• W2738204425 hasAuthorship W2738204425A5009557371 @default.
• W2738204425 hasAuthorship W2738204425A5012581038 @default.
• W2738204425 hasAuthorship W2738204425A5062296541 @default.
• W2738204425 hasAuthorship W2738204425A5083253755 @default.
• W2738204425 hasAuthorship W2738204425A5087325737 @default.
• W2738204425 hasConcept C11268172 @default.
• W2738204425 hasConcept C13965031 @default.
• W2738204425 hasConcept C178790620 @default.
• W2738204425 hasConcept C179104552 @default.
• W2738204425 hasConcept C183882617 @default.
• W2738204425 hasConcept C184651966 @default.
• W2738204425 hasConcept C185592680 @default.
• W2738204425 hasConcept C2776201271 @default.
• W2738204425 hasConcept C2776300020 @default.
• W2738204425 hasConcept C2778913249 @default.
• W2738204425 hasConceptScore W2738204425C11268172 @default.
• W2738204425 hasConceptScore W2738204425C13965031 @default.
• W2738204425 hasConceptScore W2738204425C178790620 @default.
• W2738204425 hasConceptScore W2738204425C179104552 @default.
• W2738204425 hasConceptScore W2738204425C183882617 @default.

• next