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• W2738523515 abstract "We consider the thermodynamics and kinetics of oxygen incorporation in the alkaline earth fluor ides, basing our discussion on the results of calculated energies of formation of a range of defects and defect clusters. Our results strongly suggest that oxygen may be incorporated only by hydrolysis and not by oxidation, and that the reaction will only occur in doped crystals. We propose a mechanism for the reaction, involving proton exchange at the surface of the crystals followed by diffusion of hydroxyl ions into the crystal; there they react with dopant-interstitial complexes to produce dopant-oxide complexes of types that have been detected in spin resonance studies." @default.
• W2738523515 created "2017-07-31" @default.
• W2738523515 creator A5042572313 @default.
• W2738523515 date "1977-01-01" @default.
• W2738523515 modified "2023-09-24" @default.
• W2738523515 title "Oxygen incorporation in the alkaline earth fluorides" @default.
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• W2738523515 doi "https://doi.org/10.1016/0022-3697(77)90039-7" @default.
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