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• W2738778051 abstract "The synthesis of hydrophilic crosslinked poly(methacrylic acid) (PMAA) nanoparticles usually involves the use of organic solvents. In this study, a novel, facile and efficient route was developed for the “green” fabrication of PMAA nanoparticles in water. Crosslinked PMAA nanoparticles were prepared via simply copolymerizing MAA with crosslinker N,N′-methylenebisacrylamide in an aqueous solution of polyoxyethylene (20) sorbitan monolaurate (tween 20), sodium dodecylsulfate and 2,2′-azodiisobutyronitrile. The water-soluble PMAA chains produced in-situ are converted into water-insoluble PMAA/tween 20 complexes via hydrogen bonding interactions with tween 20. This leads to the homogenous nucleation and deposition growth of PMAA nanoparticles, thus realizing the fabrication of crosslinked PMAA nanoparticles in water. Crosslinked PMAA nanoparticles with a z-average hydrodynamic diameter in the range of 99–480 nm and a normalized swelling ratio in the range of 1.3–3.1 were obtained by varying the reaction parameters. The pH-sensitivity, biocompatibility and carboxyl functional groups make the crosslinked PMAA nanoparticles ideal candidates for various biomedical applications." @default.
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• W2738778051 date "2017-10-01" @default.
• W2738778051 modified "2023-09-30" @default.
• W2738778051 title "A facile, efficient and “green” route to pH-responsive crosslinked poly(methacrylic acid) nanoparticles" @default.
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• W2738778051 doi "https://doi.org/10.1016/j.colsurfa.2017.07.062" @default.
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