Matches in SemOpenAlex for { <https://semopenalex.org/work/W2738962444> ?p ?o ?g. }
- W2738962444 endingPage "17243" @default.
- W2738962444 startingPage "17235" @default.
- W2738962444 abstract "In this work, we report complex kinetic phenomena observed during the reduction of NO2 on rhodium model catalysts followed by field emission microscopy (FEM). This technique uses samples prepared as sharp tips, mimicking the size and shape of one catalytic nanoparticle. The method enables one to study catalytic reactions in real time down to the nanoscale. Running the NO2 + H2 reaction on Rh at 450 K and in the 10–5 Pa range, we observe nonlinear behaviors on the facets corresponding to {011} and {012} crystallographic orientations. The emergence of nonlinearities is studied as a function of the control parameters, and the particular case of self-sustained periodic oscillations is analyzed in detail. The corresponding bifurcation diagram shows that the oscillations appear via a supercritical Hopf bifurcation. It is moreover possible to reconstruct the underlying dynamical attractor—here, the limit cycle—using the time-delay embedding method. Different possible mechanisms of reaction leading to these oscillations are discussed." @default.
- W2738962444 created "2017-07-31" @default.
- W2738962444 creator A5004834295 @default.
- W2738962444 creator A5053438615 @default.
- W2738962444 creator A5061237242 @default.
- W2738962444 date "2017-08-02" @default.
- W2738962444 modified "2023-10-16" @default.
- W2738962444 title "NO<sub>2</sub> Hydrogenation on Rh Catalysts: Bifurcations and Oscillations at the Nanoscale" @default.
- W2738962444 cites W1518816284 @default.
- W2738962444 cites W1539125800 @default.
- W2738962444 cites W1637655637 @default.
- W2738962444 cites W1840973841 @default.
- W2738962444 cites W1963496971 @default.
- W2738962444 cites W1967978339 @default.
- W2738962444 cites W1974214441 @default.
- W2738962444 cites W1978697091 @default.
- W2738962444 cites W1979957032 @default.
- W2738962444 cites W1981782401 @default.
- W2738962444 cites W1983147857 @default.
- W2738962444 cites W1985723814 @default.
- W2738962444 cites W1986123495 @default.
- W2738962444 cites W1988824993 @default.
- W2738962444 cites W1999635656 @default.
- W2738962444 cites W2006877492 @default.
- W2738962444 cites W2015572127 @default.
- W2738962444 cites W2026736605 @default.
- W2738962444 cites W2028628295 @default.
- W2738962444 cites W2031092275 @default.
- W2738962444 cites W2031201447 @default.
- W2738962444 cites W2031365860 @default.
- W2738962444 cites W2034031156 @default.
- W2738962444 cites W2035316753 @default.
- W2738962444 cites W2037424617 @default.
- W2738962444 cites W2038094602 @default.
- W2738962444 cites W2040317292 @default.
- W2738962444 cites W2040704490 @default.
- W2738962444 cites W2041672867 @default.
- W2738962444 cites W2042693593 @default.
- W2738962444 cites W2043769488 @default.
- W2738962444 cites W2048272714 @default.
- W2738962444 cites W2056721316 @default.
- W2738962444 cites W2056838693 @default.
- W2738962444 cites W2062708993 @default.
- W2738962444 cites W2065769400 @default.
- W2738962444 cites W2066327724 @default.
- W2738962444 cites W2068253290 @default.
- W2738962444 cites W2072735642 @default.
- W2738962444 cites W2074933229 @default.
- W2738962444 cites W2084950481 @default.
- W2738962444 cites W2086158921 @default.
- W2738962444 cites W2091193556 @default.
- W2738962444 cites W2106065962 @default.
- W2738962444 cites W2115171184 @default.
- W2738962444 cites W2131908417 @default.
- W2738962444 cites W2134733372 @default.
- W2738962444 cites W2151357746 @default.
- W2738962444 cites W2161606023 @default.
- W2738962444 cites W2168374601 @default.
- W2738962444 cites W2525437570 @default.
- W2738962444 cites W2600406215 @default.
- W2738962444 cites W2610591096 @default.
- W2738962444 cites W3180042145 @default.
- W2738962444 cites W4206511281 @default.
- W2738962444 cites W4245573985 @default.
- W2738962444 cites W7868203 @default.
- W2738962444 cites W844552389 @default.
- W2738962444 doi "https://doi.org/10.1021/acs.jpcc.7b04123" @default.
- W2738962444 hasPublicationYear "2017" @default.
- W2738962444 type Work @default.
- W2738962444 sameAs 2738962444 @default.
- W2738962444 citedByCount "6" @default.
- W2738962444 countsByYear W27389624442018 @default.
- W2738962444 countsByYear W27389624442019 @default.
- W2738962444 countsByYear W27389624442020 @default.
- W2738962444 crossrefType "journal-article" @default.
- W2738962444 hasAuthorship W2738962444A5004834295 @default.
- W2738962444 hasAuthorship W2738962444A5053438615 @default.
- W2738962444 hasAuthorship W2738962444A5061237242 @default.
- W2738962444 hasConcept C118419359 @default.
- W2738962444 hasConcept C121332964 @default.
- W2738962444 hasConcept C134306372 @default.
- W2738962444 hasConcept C154945302 @default.
- W2738962444 hasConcept C155672457 @default.
- W2738962444 hasConcept C158622935 @default.
- W2738962444 hasConcept C159467904 @default.
- W2738962444 hasConcept C161790260 @default.
- W2738962444 hasConcept C164380108 @default.
- W2738962444 hasConcept C171250308 @default.
- W2738962444 hasConcept C172435161 @default.
- W2738962444 hasConcept C185592680 @default.
- W2738962444 hasConcept C18762648 @default.
- W2738962444 hasConcept C192562407 @default.
- W2738962444 hasConcept C2781349735 @default.
- W2738962444 hasConcept C33923547 @default.
- W2738962444 hasConcept C41008148 @default.
- W2738962444 hasConcept C41608201 @default.
- W2738962444 hasConcept C41971866 @default.
- W2738962444 hasConcept C45206210 @default.