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• W2738973561 startingPage "1701272" @default.
• W2738973561 abstract "1,4-Dimethoxybenzene derivatives are materials of choice for use as catholytes in non-aqueous redox flow batteries, as they exhibit high open-circuit potentials and excellent electrochemical reversibility. However, chemical stability of these materials in their oxidized form needs to be improved. Disubstitution in the arene ring is used to suppress parasitic reactions of their radical cations, but this does not fully prevent ring-addition reactions. By incorporating bicyclic substitutions and ether chains into the dialkoxybenzenes, a novel catholyte molecule, 9,10-bis(2-methoxyethoxy)-1,2,3,4,5,6,7,8-octahydro-1,4:5,8-dimethanenoanthracene (BODMA), is obtained and exhibits greater solubility and superior chemical stability in the charged state. A hybrid flow cell containing BODMA is operated for 150 charge–discharge cycles with a minimal loss of capacity." @default.
• W2738973561 created "2017-07-31" @default.
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• W2738973561 date "2017-07-21" @default.
• W2738973561 modified "2023-10-17" @default.
• W2738973561 title "Annulated Dialkoxybenzenes as Catholyte Materials for Non‐aqueous Redox Flow Batteries: Achieving High Chemical Stability through Bicyclic Substitution" @default.
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• W2738973561 doi "https://doi.org/10.1002/aenm.201701272" @default.
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