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- W2740202318 abstract "Abstract Four new (pyrazol-1-yl)phenylmethanone ligands and their palladium(II) complexes were synthesized and characterized by various analytical techniques. The electronic properties of substituents on the phenyl ring of the ligand have significant effects on the structures as well as the catalytic properties of the complexes toward ethylene oligomerization and the subsequent Friedel-Crafts alkylation of toluene by the ethylene oligomers. Electron-withdrawing groups ( ca. Cl and F) of the ligands contributed to the formation of binuclear palladium complexes, whereas electron-donating groups ( ca . H and CH 3 ) resulted in the formation of mononuclear complexes. These complexes on activation with EtAlCl 2 form active catalysts which dimerize ethylene to mainly butenes (C4) and subsequent Friedel-Crafts alkylation of toluene by butenes to regioisomers of butyltoluenes. This is the first example of pyrazolyl palladium(II) compounds that perform this tandem reaction of oligomerization and Friedel-Crafts alkylation." @default.
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- W2740202318 date "2017-10-01" @default.
- W2740202318 modified "2023-09-27" @default.
- W2740202318 title "Electronic effects on the structures and catalytic properties of (pyrazol-1-yl)phenylmethanone palladium(II) complexes" @default.
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- W2740202318 doi "https://doi.org/10.1016/j.jorganchem.2017.07.033" @default.
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