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- W2740293669 abstract "The synthesis of the new bis‐heteroleptic Ru II complex [(tbbpy) 2 Ru(dptpphz)](PF 6 ) 2 ( 7 ), that exhibits a tetradentate coordination sphere for a second metal centre, and its characterization are presented. The complex shows similar photostability and redox properties regarding the first ligand‐centred reductions compared to its tpphz analogue. Concentration‐dependent NMR investigations were performed and a dimerization constant (KD = 83 ± 5) could be calculated, which was significantly lower than that of other tpphz systems. Photophysical investigations reveal a stabilizing effect of the two electron‐withdrawing 2‐pyridyl substituents on π–π* transition of the phenazine sphere. The typical H 2 O‐induced light‐switch effects have also been observed. To further highlight the potential of the tetradentate coordination site, the Zn II adduct of 7 was prepared and preliminary studied." @default.
- W2740293669 created "2017-08-08" @default.
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- W2740293669 date "2017-09-13" @default.
- W2740293669 modified "2023-10-16" @default.
- W2740293669 title "Synthesis and Characterization of a Ruthenium(II) Complex for the Development of Supramolecular Photocatalysts Containing Multidentate Coordination Spheres" @default.
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- W2740293669 doi "https://doi.org/10.1002/ejic.201700565" @default.
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