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- W2740392703 abstract "Summary Novel mixed-ligand complexes of Ag j and Au I containing triphenylphosphine (TPP) and heterocyclic thiones, of general formula [TPP-M-L]C1 and [(TPP)2-M-LIC1, where L = imidazolidine-2-thione (Imt), 1, 3-diazinine-2thione (Diaz) or N-isopropylimidazolidine-2-thione (iPrImt) have been prepared. The spectroscopic data are consistent with S-donation in all complexes. The magnitude of high-field shift in carbon-13 n.m.r, of the thioureide carbon on complexation is interpreted in terms of coordination geometry around the metal atoms. The mixed-ligand complexes are structurally similar to some of the commonly used antiarthritic Au ~ drugs and are thus potentially useful in chemotherapy." @default.
- W2740392703 created "2017-08-08" @default.
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- W2740392703 date "1990-01-01" @default.
- W2740392703 modified "2023-09-24" @default.
- W2740392703 title "silver(l) with heterocyclic" @default.
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- W2740392703 hasPublicationYear "1990" @default.
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