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- W2740420214 abstract "This paper reports that N-arylenamines can be converted into quinoxalines via tandem azidation/intramolecular CH amination under visible light irradiation by using 1-azidyl-1,2-benziodoxole as the azidating agent. The substituent was found to have a critical influence on the reaction, and thus different conditions were required to fit the substrates of varied structural features. The conversion of N-aryl-3-arylenamine esters into the corresponding quinoxalines proceeded well under metal-free conditions, whereas Cu(OAc)2 was required when N-aryl-3-trifluoromethyl enamine esters were used as the substrates. This method was also applied to the preparation of 2,3-diarylquinoxalines by using Ru(bpy)3Cl2 as the photoredox catalyst. The reactions revealed herein provide an efficient approach towards quinoxalines." @default.
- W2740420214 created "2017-08-08" @default.
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- W2740420214 date "2018-03-01" @default.
- W2740420214 modified "2023-09-27" @default.
- W2740420214 title "Visible light-promoted tandem azidation/cyclization of N-arylenamines towards quinoxalines" @default.
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- W2740420214 doi "https://doi.org/10.1016/j.jphotochem.2017.07.043" @default.
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