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- W2740740572 abstract "The development of robust and efficient strategies to access structurally diverse drug-like compound collections remains an important challenge for small molecule probe development and drug discovery. Following a build/couple/pair strategy we have established bidirectional approach to unprecedented benzoxazepines by employing a Pictet-Spengler/aza-Michael addition cascade and Schiff base/aza-Michael addition/reduction protocols, respectively. The corresponding β-carboline-fused benzoxazepines and peripherally substituted benzoxazepines are isolated in high diastereoselectivity, good to excellent yields and have, to the best of our knowledge, never been reported." @default.
- W2740740572 created "2017-08-08" @default.
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- W2740740572 date "2017-09-07" @default.
- W2740740572 modified "2023-09-26" @default.
- W2740740572 title "Modular Bi-Directional One-Pot Strategies for the Diastereoselective Synthesis of Structurally Diverse Collections of Constrained β-Carboline-Benzoxazepines" @default.
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- W2740740572 doi "https://doi.org/10.1002/chem.201702495" @default.
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