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• W2740935675 startingPage "12557" @default.
• W2740935675 abstract "Abstract The imidazolium chloride [C 3 H 3 N(C 3 H 6 NMe 2 )N{C(Me)(=NDipp)}]Cl ( 1 ; Dipp=2,6‐diisopropyl phenyl), a potential precursor to a tritopic N imine C NHC N amine pincer‐type ligand, reacted with [Ni(cod) 2 ] to give the Ni I ‐Ni I complex 2 , which contains a rare cod‐derived η 3 ‐allyl‐type bridging ligand. The implied intermediate formation of a nickel hydride through oxidative addition of the imidazolium C−H bond did not occur with the symmetrical imidazolium chloride [C 3 H 3 N 2 {C(Me)(=NDipp)} 2 ]Cl ( 3 ). Instead, a Ni−C(sp 3 ) bond was formed, leading to the neutral N imine CHN imine pincer‐type complex Ni[C 3 H 3 N 2 {C(Me)(=NDipp)} 2 ]Cl ( 4 ). Theoretical studies showed that this highly unusual feature in nickel NHC chemistry is due to steric constraints induced by the N substituents, which prevent Ni−H bond formation. Remarkably, ethylene inserted into the C(sp 3 )−H bond of 4 without nickel hydride formation, thus suggesting new pathways for the alkylation of non‐activated C−H bonds." @default.
• W2740935675 created "2017-08-08" @default.
• W2740935675 creator A5028479648 @default.
• W2740935675 creator A5063605867 @default.
• W2740935675 creator A5073328308 @default.
• W2740935675 creator A5084817853 @default.
• W2740935675 date "2017-08-31" @default.
• W2740935675 modified "2023-10-14" @default.
• W2740935675 title "Tritopic NHC Precursors: Unusual Nickel Reactivity and Ethylene Insertion into a C(sp ³ )–H Bond" @default.
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• W2740935675 doi "https://doi.org/10.1002/anie.201706581" @default.
• W2740935675 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28758718" @default.
• W2740935675 hasPublicationYear "2017" @default.
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