FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2740937209> ?p ?o ?g. }

• W2740937209 abstract "Reaction between N,N’-2,6-bis(3-pyridylmethyl)pyridine dicarboxamide (L) with dichloropalladium(II) 2,2’-bipyridine [PdCl2(2,2’-bipy)] and dichloropalladium(II) ethylenediamine [PdCl2(en)] gave rise to two novel metallo-macrocycles, [Pd(L)(2,2’-bipy)](PF6)2 (A1) and [Pd(en)(L)](PF6)2·H2O·2CH3OH (A2), respectively. These complexes were characterized by spectroscopic techniques such as Fourier Transform Infrared (FT-IR), Nuclear Magnetic Resonance (NMR), electrospray ionization mass spectrometry (ESI-MS) and elemental analysis. The studies on the interactions between the protons of the ligand and the protons of the ancillary ligands (etc. bipy, en) of the complexes were identified by using two dimensional NMR techniques such as Nuclear Overhauser Spectroscopy (2D NOESY) and correlation spectroscopy (COSY). X-ray crystallography shows that complex A2 form a bowl-like structure with one hexafluorophosphate anions encapsulated in the molecule cavity. The hexafluorophosphate anions form weak interaction with the ancillary ligand ethylenediamine (N-H … F, d = 2.379, D = 3.113 A) which stabilized by weak C-H  F hydrogen bonding. The presence of weak anion- contact is also observed between the anion and the central pyridine of the metallo-macrocycle. Further analysis by diffusion-ordered spectroscopy (DOSY) has shown that the diffusion rates of complexes A1 and A2 are lower from the theoretical value. This might be due to the complexing of hexafluorophosphate anions that increase the hydrodynamic radii of the complexes." @default.
• W2740937209 created "2017-08-08" @default.
• W2740937209 creator A5006522838 @default.
• W2740937209 creator A5014254461 @default.
• W2740937209 creator A5060018496 @default.
• W2740937209 creator A5074357556 @default.
• W2740937209 creator A5086606027 @default.
• W2740937209 creator A5089396935 @default.
• W2740937209 date "2015-01-01" @default.
• W2740937209 modified "2023-09-23" @default.
• W2740937209 title "SYNTHESIS, STRUCTURAL AND SPECTROSCOPIC STUDIES OF PALLADIUM(II) METALLO-MACROCYLES CONTAINING ANCILLARY BLOCKING LIGANDS AND N,N'-2,6-BIS(3-PYRIDYLMETHYL)PYRIDINE DICARBOXAMIDE (Sintesis, Struktur Dan Kajian Spektroskopik Makrosiklik-Berlogam Paladium(II) Terkandung Ligan Sampingan dan 2,6-Bis(3-Piridilmetil)Piridin Dikarbosamida)" @default.
• W2740937209 cites W1599563409 @default.
• W2740937209 cites W1966204586 @default.
• W2740937209 cites W1977961375 @default.
• W2740937209 cites W1983759499 @default.
• W2740937209 cites W1987293150 @default.
• W2740937209 cites W1997355599 @default.
• W2740937209 cites W2006589636 @default.
• W2740937209 cites W2015641607 @default.
• W2740937209 cites W2016737521 @default.
• W2740937209 cites W2017042218 @default.
• W2740937209 cites W2017220550 @default.
• W2740937209 cites W2030183106 @default.
• W2740937209 cites W2036761286 @default.
• W2740937209 cites W2037332917 @default.
• W2740937209 cites W2060090426 @default.
• W2740937209 cites W2065665134 @default.
• W2740937209 cites W2073718973 @default.
• W2740937209 cites W2076279192 @default.
• W2740937209 cites W2076718421 @default.
• W2740937209 cites W2079362438 @default.
• W2740937209 cites W2084947621 @default.
• W2740937209 cites W2089419010 @default.
• W2740937209 cites W2098292174 @default.
• W2740937209 cites W2103680519 @default.
• W2740937209 cites W2111308793 @default.
• W2740937209 cites W2111765539 @default.
• W2740937209 cites W2126651534 @default.
• W2740937209 cites W2132680031 @default.
• W2740937209 cites W2144468837 @default.
• W2740937209 cites W2145196458 @default.
• W2740937209 cites W2148066840 @default.
• W2740937209 cites W2150512704 @default.
• W2740937209 cites W2328866692 @default.
• W2740937209 hasPublicationYear "2015" @default.
• W2740937209 type Work @default.
• W2740937209 sameAs 2740937209 @default.
• W2740937209 citedByCount "0" @default.
• W2740937209 crossrefType "journal-article" @default.
• W2740937209 hasAuthorship W2740937209A5006522838 @default.
• W2740937209 hasAuthorship W2740937209A5014254461 @default.
• W2740937209 hasAuthorship W2740937209A5060018496 @default.
• W2740937209 hasAuthorship W2740937209A5074357556 @default.
• W2740937209 hasAuthorship W2740937209A5086606027 @default.
• W2740937209 hasAuthorship W2740937209A5089396935 @default.
• W2740937209 hasConcept C112887158 @default.
• W2740937209 hasConcept C116569031 @default.
• W2740937209 hasConcept C145148216 @default.
• W2740937209 hasConcept C154881586 @default.
• W2740937209 hasConcept C155647269 @default.
• W2740937209 hasConcept C161790260 @default.
• W2740937209 hasConcept C170493617 @default.
• W2740937209 hasConcept C178790620 @default.
• W2740937209 hasConcept C179104552 @default.
• W2740937209 hasConcept C185592680 @default.
• W2740937209 hasConcept C19549132 @default.
• W2740937209 hasConcept C2777598222 @default.
• W2740937209 hasConcept C2779485729 @default.
• W2740937209 hasConcept C2780728571 @default.
• W2740937209 hasConcept C32909587 @default.
• W2740937209 hasConcept C40684141 @default.
• W2740937209 hasConcept C502130503 @default.
• W2740937209 hasConcept C55493867 @default.
• W2740937209 hasConcept C66974803 @default.
• W2740937209 hasConcept C71240020 @default.
• W2740937209 hasConcept C8010536 @default.
• W2740937209 hasConceptScore W2740937209C112887158 @default.
• W2740937209 hasConceptScore W2740937209C116569031 @default.
• W2740937209 hasConceptScore W2740937209C145148216 @default.
• W2740937209 hasConceptScore W2740937209C154881586 @default.
• W2740937209 hasConceptScore W2740937209C155647269 @default.
• W2740937209 hasConceptScore W2740937209C161790260 @default.
• W2740937209 hasConceptScore W2740937209C170493617 @default.
• W2740937209 hasConceptScore W2740937209C178790620 @default.
• W2740937209 hasConceptScore W2740937209C179104552 @default.
• W2740937209 hasConceptScore W2740937209C185592680 @default.
• W2740937209 hasConceptScore W2740937209C19549132 @default.
• W2740937209 hasConceptScore W2740937209C2777598222 @default.
• W2740937209 hasConceptScore W2740937209C2779485729 @default.
• W2740937209 hasConceptScore W2740937209C2780728571 @default.
• W2740937209 hasConceptScore W2740937209C32909587 @default.
• W2740937209 hasConceptScore W2740937209C40684141 @default.
• W2740937209 hasConceptScore W2740937209C502130503 @default.
• W2740937209 hasConceptScore W2740937209C55493867 @default.
• W2740937209 hasConceptScore W2740937209C66974803 @default.
• W2740937209 hasConceptScore W2740937209C71240020 @default.
• W2740937209 hasConceptScore W2740937209C8010536 @default.
• W2740937209 hasLocation W27409372091 @default.
• W2740937209 hasOpenAccess W2740937209 @default.
• W2740937209 hasPrimaryLocation W27409372091 @default.

• next