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• W2741326160 endingPage "9562" @default.
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• W2741326160 abstract "Introducing another chromophore into a luminescent MOF is a potential way to assembling novel dual-emissive luminescent materials. Putting the chromophore, for which luminescence can be enhanced by Zn2+ ion, into MOF-5 by the bottle around ship strategy is a simple but efficient synthesis method to realize such dual-emissive materials. According to this strategy, a novel dual-emissive luminescent composite material [Zn2(HL)3]+@MOF-5 was constructed by loading the [La3(HL)2L2(NO3)3H2O] (1) (H2L = 7,7'-(ethane-1,1'-diyl)8-hydro-quinoline) into MOF-5, in which the [Zn2(HL)3]+ anions were transformed from 1 with the existence of Zn2+. The dual-emissive composite materials show excellent luminescence with two emissions of MOF-5 at 410 nm and [Zn2(HL)3]+ at 524 nm. Furthermore, by combining characteristics of MOF-5 and the guest chromophore, the composite material is highly selectively sensitive toward Al3+ and monoethanolamine, which makes [Zn2(HL)3]+@MOF-5 a potential self-calibrated fluorescence sensor." @default.
• W2741326160 created "2017-08-08" @default.
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• W2741326160 date "2017-07-31" @default.
• W2741326160 modified "2023-10-17" @default.
• W2741326160 title "The Design of Dual-Emissive Composite Material [Zn₂(HL)₃]⁺@MOF-5 as Self-Calibrating Luminescent Sensors of Al³⁺ Ions and Monoethanolamine" @default.
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• W2741326160 doi "https://doi.org/10.1021/acs.inorgchem.7b00939" @default.
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