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- W2741830752 abstract "We report a Pd-catalyzed stereospecific α-arylation of optically pure 2,3-epoxy-1,1,1-trifluoropropane (TFPO). This method allows for the direct and reliable preparation of optically pure 2-CF3-2-(hetero)aryloxiranes, which are precursors to many CF3-substituted tertiary alcohols. The use of continuous-flow methods has allowed the deprotonation of TFPO and subsequent zincation at higher temperature compared to that under traditional batch conditions." @default.
- W2741830752 created "2017-08-08" @default.
- W2741830752 creator A5039233288 @default.
- W2741830752 creator A5058435392 @default.
- W2741830752 date "2017-08-10" @default.
- W2741830752 modified "2023-10-17" @default.
- W2741830752 title "Palladium-Catalyzed Negishi Coupling of α-CF<sub>3</sub> Oxiranyl Zincate: Access to Chiral CF<sub>3</sub>-Substituted Benzylic Tertiary Alcohols" @default.
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- W2741830752 doi "https://doi.org/10.1021/jacs.7b06630" @default.
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