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- W2742046874 abstract "Abstract The carbocyclization of non‐conjugated dienes mediated by organometallics is an important reaction for the synthesis of a variety of carbocyclic derivatives, but the direct annulation of dienes with an inert C−H bond of a substrate has remained unexplored to date. We herein report a series of novel rare‐earth dialkyl complexes bearing a phosphinoamide anion and demonstrate that the combination of a mono(phosphinoamido)‐ligated scandium dialkyl complex with B(C 6 F 5 ) 3 results in an excellent catalyst for the cis ‐selective cyclization of 1,5‐dienes with the ortho ‐C(sp 2 )−H bond of pyridines to afford a new family of pyridyl‐functionalized 1,3‐disubstituted cyclopentane derivatives containing monocyclic, bicyclic, spirocyclic, and heterocyclic skeletons in moderate to excellent yields with high diastereoselectivities ( cis / trans up to 99:1)." @default.
- W2742046874 created "2017-08-08" @default.
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- W2742046874 date "2017-11-08" @default.
- W2742046874 modified "2023-10-10" @default.
- W2742046874 title "Diastereoselective Cyclization of 1,5-Dienes with the C−H Bond of Pyridine Catalyzed by a Cationic Mono(phosphinoamide) Alkyl Scandium Complex" @default.
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- W2742046874 doi "https://doi.org/10.1002/cctc.201700980" @default.
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