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• W2742204633 endingPage "12106" @default.
• W2742204633 startingPage "12102" @default.
• W2742204633 abstract "We report the rational design of metal-organic layers (MOLs) that are built from [Hf6 O4 (OH)4 (HCO2 )6 ] secondary building units (SBUs) and Ir[bpy(ppy)2 ]+ - or [Ru(bpy)3 ]2+ -derived tricarboxylate ligands (Hf-BPY-Ir or Hf-BPY-Ru; bpy=2,2'-bipyridine, ppy=2-phenylpyridine) and their applications in X-ray-induced photodynamic therapy (X-PDT) of colon cancer. Heavy Hf atoms in the SBUs efficiently absorb X-rays and transfer energy to Ir[bpy(ppy)2 ]+ or [Ru(bpy)3 ]2+ moieties to induce PDT by generating reactive oxygen species (ROS). The ability of X-rays to penetrate deeply into tissue and efficient ROS diffusion through ultrathin 2D MOLs (ca. 1.2 nm) enable highly effective X-PDT to afford superb anticancer efficacy." @default.
• W2742204633 created "2017-08-17" @default.
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• W2742204633 date "2017-08-25" @default.
• W2742204633 modified "2023-09-30" @default.
• W2742204633 title "Nanoscale Metal-Organic Layers for Deeply Penetrating X-ray-Induced Photodynamic Therapy" @default.
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• W2742204633 doi "https://doi.org/10.1002/anie.201704828" @default.
• W2742204633 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/5666692" @default.
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• W2742204633 hasPublicationYear "2017" @default.
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