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- W2742437943 abstract "The sodium salt of poly(dG-dC) is known to exhibit a B rightarrow Z transition in the presence of various previous termcationsnext term and 60% alcohol. We here show that the lithium salt of poly(dG-dC) does not undergo B rightarrow Z transition in the presence of 60% alcohol since $Li^+$ with its large hydration shell cannot stabilize the Z-form. On the other hand, high concentrations of $Mg^{2+}$ or micromolar concentrations of the cobalt hexamine complex which are known to stabilize the Z-form can compete with $Li^+$ for charge neutralization and hence bring about a B rightarrow Z transition in the same polymer. From the model building studies the mode of action of the cobalt—hexamine complex in stabilizing the Z-form is postulated." @default.
- W2742437943 created "2017-08-17" @default.
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- W2742437943 date "1983-11-01" @default.
- W2742437943 modified "2023-09-27" @default.
- W2742437943 title "Critical cation balance in B rightarrow Z transition: role of $Li^+$" @default.
- W2742437943 hasPublicationYear "1983" @default.
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