Matches in SemOpenAlex for { <https://semopenalex.org/work/W2742612084> ?p ?o ?g. }
- W2742612084 endingPage "610" @default.
- W2742612084 startingPage "603" @default.
- W2742612084 abstract "Abstract Two porous metal-organic frameworks (MOFs) incorporating pentanuclear Yb(III) clusters and pyridyl-supported tetracarboxylates or pyridyl carboxylic acid-supported tetracarboxylates, Yb-DDPY and Yb-DDIA, are presented, in which the pentanuclear Yb(III) cluster shows uncommon trigonal bipyramidal geometry. Furthermore, the pentanuclear Yb(III) clusters are extended by tetracarboxylates to form a 3D porous framework with uniform M12L8-cages constructed by 12 pentanuclear Yb(III) clusters and 8 tetracarboxylates with the size of ca. 20 A × 17 A. Their highly CO2 uptake capacity and the existence of Lewis acidic sites make these MOFs promising catalysts for the chemical conversion of CO2. These MOFs demonstrate good catalytic activities and recyclability in the cycloaddition of CO2 and epoxides at 60 °C under 1.0 MPa pressure or at room temperature and atmospheric pressure. In addition, the synergistic effect of the Bronsted acidic –COOH groups and the Lewis acidic Yb(III) sites makes Yb-DDIA exhibit higher catalytic activity towards the cycloaddition of CO2 and epoxides." @default.
- W2742612084 created "2017-08-17" @default.
- W2742612084 creator A5040647242 @default.
- W2742612084 creator A5042104519 @default.
- W2742612084 creator A5048826739 @default.
- W2742612084 creator A5049053873 @default.
- W2742612084 creator A5066245492 @default.
- W2742612084 date "2017-12-01" @default.
- W2742612084 modified "2023-10-18" @default.
- W2742612084 title "Pentanuclear Yb(III) cluster-based metal-organic frameworks as heterogeneous catalysts for CO2 conversion" @default.
- W2742612084 cites W1967109824 @default.
- W2742612084 cites W1973398033 @default.
- W2742612084 cites W1974230931 @default.
- W2742612084 cites W1979094582 @default.
- W2742612084 cites W1993454278 @default.
- W2742612084 cites W1995281615 @default.
- W2742612084 cites W2009046603 @default.
- W2742612084 cites W2016854671 @default.
- W2742612084 cites W2026167394 @default.
- W2742612084 cites W2030971320 @default.
- W2742612084 cites W2038064532 @default.
- W2742612084 cites W2049203091 @default.
- W2742612084 cites W2064574760 @default.
- W2742612084 cites W2068580578 @default.
- W2742612084 cites W2068957344 @default.
- W2742612084 cites W2070178225 @default.
- W2742612084 cites W2072292124 @default.
- W2742612084 cites W2075058682 @default.
- W2742612084 cites W2075118369 @default.
- W2742612084 cites W2084406030 @default.
- W2742612084 cites W2088210228 @default.
- W2742612084 cites W2088559743 @default.
- W2742612084 cites W2112307556 @default.
- W2742612084 cites W2116007269 @default.
- W2742612084 cites W2116217282 @default.
- W2742612084 cites W2131988676 @default.
- W2742612084 cites W2141939342 @default.
- W2742612084 cites W2144096517 @default.
- W2742612084 cites W2145961563 @default.
- W2742612084 cites W2149749098 @default.
- W2742612084 cites W2159253971 @default.
- W2742612084 cites W2161885649 @default.
- W2742612084 cites W2163383153 @default.
- W2742612084 cites W2165003807 @default.
- W2742612084 cites W2169085522 @default.
- W2742612084 cites W2171387881 @default.
- W2742612084 cites W2171836549 @default.
- W2742612084 cites W2206146927 @default.
- W2742612084 cites W2281882993 @default.
- W2742612084 cites W2283564633 @default.
- W2742612084 cites W2290797056 @default.
- W2742612084 cites W2298286265 @default.
- W2742612084 cites W2301164866 @default.
- W2742612084 cites W2315696731 @default.
- W2742612084 cites W2318655974 @default.
- W2742612084 cites W2319442421 @default.
- W2742612084 cites W2322788072 @default.
- W2742612084 cites W2336763575 @default.
- W2742612084 cites W2337880070 @default.
- W2742612084 cites W2337927161 @default.
- W2742612084 cites W2532267890 @default.
- W2742612084 cites W2586554840 @default.
- W2742612084 cites W2594057453 @default.
- W2742612084 cites W2605319956 @default.
- W2742612084 cites W2951427115 @default.
- W2742612084 cites W438403339 @default.
- W2742612084 doi "https://doi.org/10.1016/j.apcatb.2017.07.085" @default.
- W2742612084 hasPublicationYear "2017" @default.
- W2742612084 type Work @default.
- W2742612084 sameAs 2742612084 @default.
- W2742612084 citedByCount "72" @default.
- W2742612084 countsByYear W27426120842018 @default.
- W2742612084 countsByYear W27426120842019 @default.
- W2742612084 countsByYear W27426120842020 @default.
- W2742612084 countsByYear W27426120842021 @default.
- W2742612084 countsByYear W27426120842022 @default.
- W2742612084 countsByYear W27426120842023 @default.
- W2742612084 crossrefType "journal-article" @default.
- W2742612084 hasAuthorship W2742612084A5040647242 @default.
- W2742612084 hasAuthorship W2742612084A5042104519 @default.
- W2742612084 hasAuthorship W2742612084A5048826739 @default.
- W2742612084 hasAuthorship W2742612084A5049053873 @default.
- W2742612084 hasAuthorship W2742612084A5066245492 @default.
- W2742612084 hasConcept C147789679 @default.
- W2742612084 hasConcept C150394285 @default.
- W2742612084 hasConcept C161790260 @default.
- W2742612084 hasConcept C164866538 @default.
- W2742612084 hasConcept C178790620 @default.
- W2742612084 hasConcept C179366358 @default.
- W2742612084 hasConcept C185592680 @default.
- W2742612084 hasConcept C191897082 @default.
- W2742612084 hasConcept C192562407 @default.
- W2742612084 hasConcept C199360897 @default.
- W2742612084 hasConcept C41008148 @default.
- W2742612084 hasConcept C544153396 @default.
- W2742612084 hasConceptScore W2742612084C147789679 @default.
- W2742612084 hasConceptScore W2742612084C150394285 @default.
- W2742612084 hasConceptScore W2742612084C161790260 @default.