FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2742963420> ?p ?o ?g. }

• W2742963420 abstract "Nanocelluloses including cellulose nanocrystals (CNC), cellulose nanofibrils (CNF) and bacterial cellulose (BNC) display properties that make them suitable for the development of new, advanced materials. They are expected to play key roles in the future bioeconomy, where sustainability and biomass valorization are important concepts. This thesis work mainly focused on proposing and testing effective chemical modification strategies to endow nanocelluloses with new properties and, developing novel hybrid materials. CNF and BNC as well as Carboxymethylated CNF (CM-CNF), TEMPO-oxidized CNF (TO-CNF) and TEMPO-oxidized CNC (TO-CNC) were studied with different microscopies including Atomic Force Microscopy, spectroscopic techniques such as X-ray photoelectron spectroscopy and Fourier Transform-Infrared Spectroscopy and other surface, thermo-mechanical and magnetic instrumentation. In order to prepare the hybrid materials, nanoparticles including gold nanoparticles (Au NP), carbon quantum dots (CQD) and magnetic nanoparticles (Fe3O4 NP) were synthesized. The binding of the respective NP with nanocellulose was accomplished by using Ethylcarbodiimide hydrochloride/N-hydroxysuccinimide (EDC/NHS) and Azide-alkyne Huisgen cycloaddition (CuAAC click coupling). In turn, the NP assemblies that were installed on the surface made the nanocelluloses truly functional. Significantly, the aforementioned reactions were performed in aqueous media under relatively mild reaction conditions. Several applications of the synthesized nanoparticle-nanocellulose hybrids were demonstrated. For instance, CQD-functionalized nanocellulose was utilized for preparing luminescent nanopaper and as cytocompatible probes for bio-imaging. Magnetically responsive hybrids were designed for protein separation and an impressive separation capacity was realized for isolation of lysozyme from egg white. As very important forms of nanocellulose networks, films and nanopapers were developed as alternatives to plastics made from non-renewable carbon sources. To this end, the change of the inherent hydrophilic character of the cellulosic materials was addressed by using different strategies. For example, photo-induced (thiol-ene and thiol-yne) click reactions were demonstrated to tailor the surface wettability of films and nanopapers. The reactions were shown to be scalable and effective and can be completed within ten minutes. The developed approaches facilitated the generation of properties that are otherwise not possible for unmodified nanocelluloses. For example, CNF films with patterned surface designs and super-slippery properties were developed, making them suitable for applications relevant to drug screening, cell culture, diagnostics, anti-fouling, etc. Overall, this thesis demonstrates a body of work that expands the possible utilization of nanocelluloses in advanced materials." @default.
• W2742963420 created "2017-08-17" @default.
• W2742963420 creator A5091289006 @default.
• W2742963420 date "2017-01-01" @default.
• W2742963420 modified "2023-09-27" @default.
• W2742963420 title "Covalent Modification of Nanocellulose Towards Advanced Functional Materials" @default.
• W2742963420 hasPublicationYear "2017" @default.
• W2742963420 type Work @default.
• W2742963420 sameAs 2742963420 @default.
• W2742963420 citedByCount "0" @default.
• W2742963420 crossrefType "journal-article" @default.
• W2742963420 hasAuthorship W2742963420A5091289006 @default.
• W2742963420 hasConcept C115537861 @default.
• W2742963420 hasConcept C127413603 @default.
• W2742963420 hasConcept C155672457 @default.
• W2742963420 hasConcept C171250308 @default.
• W2742963420 hasConcept C178790620 @default.
• W2742963420 hasConcept C185592680 @default.
• W2742963420 hasConcept C188027245 @default.
• W2742963420 hasConcept C192562407 @default.
• W2742963420 hasConcept C27019838 @default.
• W2742963420 hasConcept C2777968448 @default.
• W2742963420 hasConcept C2779251873 @default.
• W2742963420 hasConcept C42360764 @default.
• W2742963420 hasConcept C69610077 @default.
• W2742963420 hasConcept C87023908 @default.
• W2742963420 hasConceptScore W2742963420C115537861 @default.
• W2742963420 hasConceptScore W2742963420C127413603 @default.
• W2742963420 hasConceptScore W2742963420C155672457 @default.
• W2742963420 hasConceptScore W2742963420C171250308 @default.
• W2742963420 hasConceptScore W2742963420C178790620 @default.
• W2742963420 hasConceptScore W2742963420C185592680 @default.
• W2742963420 hasConceptScore W2742963420C188027245 @default.
• W2742963420 hasConceptScore W2742963420C192562407 @default.
• W2742963420 hasConceptScore W2742963420C27019838 @default.
• W2742963420 hasConceptScore W2742963420C2777968448 @default.
• W2742963420 hasConceptScore W2742963420C2779251873 @default.
• W2742963420 hasConceptScore W2742963420C42360764 @default.
• W2742963420 hasConceptScore W2742963420C69610077 @default.
• W2742963420 hasConceptScore W2742963420C87023908 @default.
• W2742963420 hasLocation W27429634201 @default.
• W2742963420 hasOpenAccess W2742963420 @default.
• W2742963420 hasPrimaryLocation W27429634201 @default.
• W2742963420 hasRelatedWork W1571052956 @default.
• W2742963420 hasRelatedWork W2000313995 @default.
• W2742963420 hasRelatedWork W2068184845 @default.
• W2742963420 hasRelatedWork W2077999749 @default.
• W2742963420 hasRelatedWork W2204131821 @default.
• W2742963420 hasRelatedWork W2321864340 @default.
• W2742963420 hasRelatedWork W2591722418 @default.
• W2742963420 hasRelatedWork W2747565333 @default.
• W2742963420 hasRelatedWork W2894913330 @default.
• W2742963420 hasRelatedWork W2897798047 @default.
• W2742963420 hasRelatedWork W2907931955 @default.
• W2742963420 hasRelatedWork W2959525862 @default.
• W2742963420 hasRelatedWork W2963191383 @default.
• W2742963420 hasRelatedWork W3012496812 @default.
• W2742963420 hasRelatedWork W3014144992 @default.
• W2742963420 hasRelatedWork W3092349655 @default.
• W2742963420 hasRelatedWork W3122280484 @default.
• W2742963420 hasRelatedWork W3162369073 @default.
• W2742963420 hasRelatedWork W600358338 @default.
• W2742963420 hasRelatedWork W3131369103 @default.
• W2742963420 isParatext "false" @default.
• W2742963420 isRetracted "false" @default.
• W2742963420 magId "2742963420" @default.
• W2742963420 workType "article" @default.