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- W2743004679 abstract "We report a new strategy for the synthesis of robust hierarchical micro- and mesoporous MOFs from water stable MOFs via a selective acid etching process. The process is controlled by the size-selective diffusion of acid molecules through the MOF windows. This method enables the fine-tuning of the porosity of hierarchical MOFs, allowing for the generation of well-defined mesopores with high mesopore volume. Because of the size-selective diffusion of acid molecules, the inherent crystallinity and external morphology of the resulting MOFs are well-maintained after acid treatment. This novel strategy may provide an alternative route towards the synthesis of diverse hierarchical MOFs." @default.
- W2743004679 created "2017-08-17" @default.
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- W2743004679 date "2017-01-01" @default.
- W2743004679 modified "2023-10-14" @default.
- W2743004679 title "Hollowing out MOFs: hierarchical micro- and mesoporous MOFs with tailorable porosity via selective acid etching" @default.
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- W2743004679 doi "https://doi.org/10.1039/c7sc02886e" @default.
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