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• W2743006323 abstract "We report an original procedure for the elaboration of very high-quality single crystals of superconducting HgBa2Ca2Cu3O8+δ mercury cuprates. These single crystals are unique, with very high-quality surface paving the way for spectroscopic, transport, and thermodynamic probes in order to understand the hole-doped cuprate phase diagram. Annealing allows one to optimize Tc up to Tcmax = 133 K. The superconductivity transition width of about 2 K indicates that they are homogeneous. We show for the first time that, with adequate heat treatment, Hg-1223 can be largely underdoped and its doping level controlled. Importantly, the crystal structure was studied in detail by single-crystal X-ray diffraction, and we have identified the signature of the underdoping by a detailed sample characterization and micro-Raman spectroscopy measurements." @default.
• W2743006323 created "2017-08-17" @default.
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• W2743006323 date "2017-08-10" @default.
• W2743006323 modified "2023-09-24" @default.
• W2743006323 title "Crystal Growth and Characterization of HgBa₂Ca₂Cu₃O_8+δ Superconductors with the Highest Critical Temperature at Ambient Pressure" @default.
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• W2743006323 doi "https://doi.org/10.1021/acs.inorgchem.7b01372" @default.
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