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- W2743060307 abstract "Abstract Electrostatic interactions are characteristic of ionic liquids (ILs) and play a pivotal role in determining the formation of species when solutes are dissolved in them. The formation of new species/complexes has been investigated for certain ILs. However, such investigations have not yet focused on eutectic liquids, which are a promising class of ILs. These liquids (or liquid coordination complexes, LCCs) are rather new and are composed of cationic and anionic chloro complexes of metals. To date, these liquids have been employed as electrolytes to deposit metals and as solvents for catalysis. The present study deals with a liquid that is prepared by mixing a 1.2:1 mol ratio of AlCl 3 and 1‐butylpyrrolidine. An attempt has been made to understand the interactions of FeCl 2 with the organic molecule using spectroscopy. It was found that dissolved Fe(II) species interact mainly with the IL anion and such interactions can lead to changes in the cation of the electrolyte. Furthermore, the viability of depositing thick magnetic films of Fe and Fe–Al has been explored." @default.
- W2743060307 created "2017-08-17" @default.
- W2743060307 creator A5024974314 @default.
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- W2743060307 creator A5075741024 @default.
- W2743060307 creator A5089591560 @default.
- W2743060307 date "2017-09-25" @default.
- W2743060307 modified "2023-09-27" @default.
- W2743060307 title "How a Transition-Metal(II) Chloride Interacts with a Eutectic AlCl<sub>3</sub>-Based Ionic Liquid: Insights into the Speciation of the Electrolyte and Electrodeposition of Magnetic Materials" @default.
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- W2743060307 doi "https://doi.org/10.1002/asia.201700520" @default.
- W2743060307 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/28776952" @default.
- W2743060307 hasPublicationYear "2017" @default.
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