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- W2743399573 endingPage "13050" @default.
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- W2743399573 abstract "A set of successive regioselective metalations and functionalizations of the 1,5-naphthyridine scaffold are described. A combination of Zn-, Mg-, and Li-TMP (TMP=2,2,6,6-tetramethylpiperidyl) bases and the presence or absence of a Lewis acid (BF3 ⋅OEt2 ) allows the introduction of up to three substituents to the 1,5-naphthyridine core. Also, a novel halogen dance reaction was discovered upon metalation of an 8-iodo-2,4-trifunctionalized 1,5-naphthyridine allowing a fourth regioselective functionalization. Additionally, reactions leading to key 1,5-naphthyridines for the preparation of OLED materials and a potential antibacterial agent were performed." @default.
- W2743399573 created "2017-08-17" @default.
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- W2743399573 date "2017-08-23" @default.
- W2743399573 modified "2023-10-02" @default.
- W2743399573 title "Zn-, Mg-, and Li-TMP Bases for the Successive Regioselective Metalations of the 1,5-Naphthyridine Scaffold (TMP=2,2,6,6-Tetramethylpiperidyl)" @default.
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- W2743399573 doi "https://doi.org/10.1002/chem.201703638" @default.
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