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- W2743660129 abstract "The electrodeposition of platinum nanoparticles (PtNPs) on multiwall carbon nanotubes (MWCNTs)/fluorine-doped tin oxide glass (FTO) was investigated. Nucleation and growth mechanisms were studied via Scharifker and Hills model. Chronoamperometry results clearly show that the electrodeposition processes are diffusion-controlled and the diffusion coefficient is $$1.5times 10^{-5 },hbox {cm}^{2}hbox {/s}$$ . The semi-spherical particles with lamellar morphology were observed in 1M $$hbox {H}_{2}hbox {SO}_{4}$$ , while a petal shape was discerned in 0.5M $$hbox {H}_{2}hbox {SO}_{4}$$ . Also, dispersion, size, and uniformity of PtNPs were investigated, where the finer distribution of PtNPs with the average size less than 100 nm was obtained in 0.5M $$hbox {H}_{2}hbox {SO}_{4}$$ solution, and the mean diameter of Pt crystals was 20 nm. Finally, the electro-oxidation of methanol and oxygen reduction studied via cyclic voltammetry showed that as-prepared PtNPs/MWCNTs electrodes had superb electrocatalytic activity. Electrodeposition of platinum nanoparticles (PtNPs) on multiwall carbon nanotubes (MWCNTs)/flourine-doped tin oxide glass (FTO) was conducted successfully. The electrodeposition mechanism of PtNPs nucleation and growth on MWCNTs was studied. It was found that fine and well-distributed PtNPs/MWCNTs electrode shows a high electrochemical activity for methanol electro-oxidation." @default.
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- W2743660129 date "2017-08-08" @default.
- W2743660129 modified "2023-10-14" @default.
- W2743660129 title "Electrochemical investigation of electrodeposited platinum nanoparticles on multi walled carbon nanotubes for methanol electro-oxidation" @default.
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- W2743660129 doi "https://doi.org/10.1007/s12039-017-1346-7" @default.
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