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- W2743808168 abstract "AbstractDinuclear tin(IV) dicarboxylate complexes of the types [(n-Bu)2Sn(oda)(4-pic)]2·2H2O (1) and [(n-Bu)2Sn(pda)(H2O)]2 (2) [H2oda = oxydiacetic acid; H2pda = pyridine 2,6-dicarboxylic acid) were synthesized and characterized via physicochemical and spectroscopic studies. The spectroscopic results indicated that Sn is seven-coordinate having pentagonal bipyramidal (pbp) geometry in both complexes. The X-ray study of complex 2 further specified pentagonal bipyramidal geometry with dinuclear structural arrangement due to the involvement of carboxylate bridges formed by pda2− moiety. The crystal structure is further stabilized by different weak interactions viz., C–C⋯H, C–C⋯O, C–H⋯O, C–C⋯O, and C–H⋯H. These interactions are further supported by Hirshfeld surface analysis along with 2-D fingerprint plots of complex 2. In vitro DNA-binding studies of both complexes were evaluated using spectroscopic techniques (absorbance and fluorescence) which ascertained optimum binding affinity of both complexes. Howev..." @default.
- W2743808168 created "2017-08-17" @default.
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- W2743808168 date "2017-08-03" @default.
- W2743808168 modified "2023-09-23" @default.
- W2743808168 title "Design, synthesis and theoretical analysis of functionalized dicarboxylate moieties based on organotin(IV) dinuclear complexes: crystal structure elucidation and biological studies" @default.
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- W2743808168 doi "https://doi.org/10.1080/00958972.2017.1363889" @default.
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