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- W2743887993 abstract "A direct approach was presented to graft phosphonate groups on magnetic mesoporous carbon by an impregnation method with environmentally friendly precursors unlike the conventional methods involving a series of complicated steps and harsh conditions. Through the in situ reduction of Fe3+, magnetite particles of ∼10 nm were successfully embedded into the mesopores, which was confirmed by HR-TEM. Surface characterization by X-ray photoelectron spectroscopy and Fourier transform infrared revealed phosphonate functional groups anchored through multidentate bonding with the surface of P–Fe–CMK-3. Due to the combined advantages of mesoporous pore size (5.5 nm), phosphonate ligands (1.42 mmol g–1), and magnetic sensitivity (5.20 emu g–1), this multifunctional adsorbent captured >85% of UO22+ within 5 min and the maximum adsorption capacity was 150 mg g–1 at pH 4. The exceptionally high selectivity and efficiency of P–Fe–CMK-3 toward uranyl capture even in groundwater (Kd = 1 × 105 mL g–1), radioactive wastewater..." @default.
- W2743887993 created "2017-08-17" @default.
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- W2743887993 date "2017-08-25" @default.
- W2743887993 modified "2023-09-24" @default.
- W2743887993 title "Superparamagnetic Adsorbent Based on Phosphonate Grafted Mesoporous Carbon for Uranium Removal" @default.
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- W2743887993 doi "https://doi.org/10.1021/acs.iecr.7b01737" @default.
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