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• W2743939261 abstract "Abstract Dehydrogenation is a sustainable form of oxidation catalysis, as it avoids any primary oxidant and the waste that would accompany it. Homogeneous catalyst design for this reaction is delicate: the catalyst must have a sufficient H 2 affinity to abstract two hydrogen atoms from the substrate but not so much affinity as to fail to release them as free H 2 . N‐Heterocyclic carbene (NHC) ligands achieve this balancing act in a series of iridium catalysts based on the Ir(IMe) 2 motif (IMe=N,N′‐dimethylimidazol‐2‐ylidene). Catalyst design also needs to account for mechanistic points outside of the catalytic cycle itself. To enter the cycle, there is often an initial precatalyst activation process, and elucidating this can lead to optimization of both precatalyst and reaction conditions. To leave the cycle, we can have reversible formation of off‐cycle species as well as an irreversible catalyst deactivation step. In our Cp*Ir(IMe) 2 Cl precatalyst for dehydrogenative oxidation, Cp* is lost in the activation step. This suggested moving to a catalyst precursor lacking the Cp*, [Ir(IMe) 2 (CO) 2 ] + . Catalyst deactivation produces a series of unusual cluster cations such as [Ir 6 (IMe) 8 (CO) 2 H 14 ] 2+ . Among applications, dehydrogenative oxidation can be useful in upgrading of biomass glycerol by conversion to lactate, as a part of hydrogen borrowing chemistry and in reversible hydrogenation/dehydrogenation for H 2 storage." @default.
• W2743939261 created "2017-08-17" @default.
• W2743939261 creator A5025514570 @default.
• W2743939261 creator A5032962378 @default.
• W2743939261 date "2017-08-10" @default.
• W2743939261 modified "2023-10-03" @default.
• W2743939261 title "Activation, Deactivation and Reversibility in a Series of Homogeneous Iridium Dehydrogenation Catalysts" @default.
• W2743939261 cites W1517883017 @default.
• W2743939261 cites W1771041933 @default.
• W2743939261 cites W1791933374 @default.
• W2743939261 cites W1963633707 @default.
• W2743939261 cites W1969200514 @default.
• W2743939261 cites W1970481590 @default.
• W2743939261 cites W1972957600 @default.
• W2743939261 cites W1977774104 @default.
• W2743939261 cites W1984280482 @default.
• W2743939261 cites W1985894920 @default.
• W2743939261 cites W1986190616 @default.
• W2743939261 cites W1989726619 @default.
• W2743939261 cites W1996808980 @default.
• W2743939261 cites W1997027171 @default.
• W2743939261 cites W2003122746 @default.
• W2743939261 cites W2004791434 @default.
• W2743939261 cites W2009652000 @default.
• W2743939261 cites W2014177778 @default.
• W2743939261 cites W2016913594 @default.
• W2743939261 cites W2018014134 @default.
• W2743939261 cites W2034535261 @default.
• W2743939261 cites W2038808854 @default.
• W2743939261 cites W2047627775 @default.
• W2743939261 cites W2059862326 @default.
• W2743939261 cites W2065195983 @default.
• W2743939261 cites W2070908196 @default.
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• W2743939261 cites W2076591334 @default.
• W2743939261 cites W2076878887 @default.
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• W2743939261 doi "https://doi.org/10.1002/ijch.201700048" @default.
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