FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2744087008> ?p ?o ?g. }

• W2744087008 endingPage "52" @default.
• W2744087008 startingPage "52" @default.
• W2744087008 abstract "Spin-crossover (SCO) behavior of a series of [Fe(X-pybox)2](ClO4)2 was investigated, where X-pybox stands for 4-X-substituted 2,6-bis(oxazolin-2-yl)pyridine with X = H, Cl, Ph, CH3O, and CH3S. We confirmed that the mother compound [Fe(H-pybox)2](ClO4)2 underwent SCO above room temperature. After X was introduced, the SCO temperatures (T1/2) were modulated as 310, 230, and 330 K for X = Cl, Ph, and CH3S, respectively. The CH3O derivative possessed the high-spin state down to 2 K. Crystallographic analysis for X = H, Cl, CH3O, and CH3S was successful, being consistent with the results of the magnetic study. Distorted coordination structures stabilize the HS (high-spin) state, and the highest degree of the coordination structure distortion is found in the CH3O derivative. A plot of T1/2 against the Hammett substituent constant σp showed a positive relation. Solution susceptometry was also performed to remove intermolecular interaction and rigid crystal lattice effects, and the T1/2’s were determined as 260, 270, 240, 170, and 210 K for X = H, Cl, Ph, CH3O, and CH3S, respectively, in acetone. The substituent effect on T1/2 became very distinct, and it is clarified that electron-donating groups stabilize the HS state." @default.
• W2744087008 created "2017-08-17" @default.
• W2744087008 creator A5042108099 @default.
• W2744087008 creator A5079680974 @default.
• W2744087008 date "2017-08-08" @default.
• W2744087008 modified "2023-09-27" @default.
• W2744087008 title "Pybox-Iron(II) Spin-Crossover Complexes with Substituent Effects from the 4-Position of the Pyridine Ring (Pybox = 2,6-Bis(oxazolin-2-yl)pyridine)" @default.
• W2744087008 cites W1774781789 @default.
• W2744087008 cites W1927892217 @default.
• W2744087008 cites W1966555688 @default.
• W2744087008 cites W1968352183 @default.
• W2744087008 cites W1978677111 @default.
• W2744087008 cites W1979525510 @default.
• W2744087008 cites W1990506391 @default.
• W2744087008 cites W2001908875 @default.
• W2744087008 cites W2020841534 @default.
• W2744087008 cites W2034641813 @default.
• W2744087008 cites W2037349442 @default.
• W2744087008 cites W2064311755 @default.
• W2744087008 cites W2066607645 @default.
• W2744087008 cites W2071748478 @default.
• W2744087008 cites W2073270981 @default.
• W2744087008 cites W2080600376 @default.
• W2744087008 cites W2096188876 @default.
• W2744087008 cites W2118928564 @default.
• W2744087008 cites W2120938115 @default.
• W2744087008 cites W2127602011 @default.
• W2744087008 cites W2142069744 @default.
• W2744087008 cites W2149115397 @default.
• W2744087008 cites W2159042504 @default.
• W2744087008 cites W2160790360 @default.
• W2744087008 cites W2175698543 @default.
• W2744087008 cites W2289931318 @default.
• W2744087008 cites W2298805510 @default.
• W2744087008 cites W2316085464 @default.
• W2744087008 cites W2318018747 @default.
• W2744087008 cites W2319538555 @default.
• W2744087008 cites W2324036762 @default.
• W2744087008 cites W2325474276 @default.
• W2744087008 cites W2326558963 @default.
• W2744087008 cites W2329654212 @default.
• W2744087008 cites W2497736744 @default.
• W2744087008 cites W2541682254 @default.
• W2744087008 cites W2604838473 @default.
• W2744087008 cites W2606898172 @default.
• W2744087008 cites W2950525462 @default.
• W2744087008 doi "https://doi.org/10.3390/inorganics5030052" @default.
• W2744087008 hasPublicationYear "2017" @default.
• W2744087008 type Work @default.
• W2744087008 sameAs 2744087008 @default.
• W2744087008 citedByCount "27" @default.
• W2744087008 countsByYear W27440870082018 @default.
• W2744087008 countsByYear W27440870082019 @default.
• W2744087008 countsByYear W27440870082020 @default.
• W2744087008 countsByYear W27440870082021 @default.
• W2744087008 countsByYear W27440870082022 @default.
• W2744087008 countsByYear W27440870082023 @default.
• W2744087008 crossrefType "journal-article" @default.
• W2744087008 hasAuthorship W2744087008A5042108099 @default.
• W2744087008 hasAuthorship W2744087008A5079680974 @default.
• W2744087008 hasBestOaLocation W27440870081 @default.
• W2744087008 hasConcept C106159729 @default.
• W2744087008 hasConcept C111771559 @default.
• W2744087008 hasConcept C115624301 @default.
• W2744087008 hasConcept C155647269 @default.
• W2744087008 hasConcept C162324750 @default.
• W2744087008 hasConcept C166950319 @default.
• W2744087008 hasConcept C178790620 @default.
• W2744087008 hasConcept C185592680 @default.
• W2744087008 hasConcept C2777222292 @default.
• W2744087008 hasConcept C2778689049 @default.
• W2744087008 hasConcept C2779485729 @default.
• W2744087008 hasConcept C2780378348 @default.
• W2744087008 hasConcept C2781213060 @default.
• W2744087008 hasConcept C32909587 @default.
• W2744087008 hasConcept C71240020 @default.
• W2744087008 hasConcept C8010536 @default.
• W2744087008 hasConceptScore W2744087008C106159729 @default.
• W2744087008 hasConceptScore W2744087008C111771559 @default.
• W2744087008 hasConceptScore W2744087008C115624301 @default.
• W2744087008 hasConceptScore W2744087008C155647269 @default.
• W2744087008 hasConceptScore W2744087008C162324750 @default.
• W2744087008 hasConceptScore W2744087008C166950319 @default.
• W2744087008 hasConceptScore W2744087008C178790620 @default.
• W2744087008 hasConceptScore W2744087008C185592680 @default.
• W2744087008 hasConceptScore W2744087008C2777222292 @default.
• W2744087008 hasConceptScore W2744087008C2778689049 @default.
• W2744087008 hasConceptScore W2744087008C2779485729 @default.
• W2744087008 hasConceptScore W2744087008C2780378348 @default.
• W2744087008 hasConceptScore W2744087008C2781213060 @default.
• W2744087008 hasConceptScore W2744087008C32909587 @default.
• W2744087008 hasConceptScore W2744087008C71240020 @default.
• W2744087008 hasConceptScore W2744087008C8010536 @default.
• W2744087008 hasIssue "3" @default.
• W2744087008 hasLocation W27440870081 @default.
• W2744087008 hasOpenAccess W2744087008 @default.
• W2744087008 hasPrimaryLocation W27440870081 @default.
• W2744087008 hasRelatedWork W2035916807 @default.

• next