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• W2745113048 startingPage "11271" @default.
• W2745113048 abstract "Although many stable disilenes (silicon-silicon doubly-bonded compounds) containing organic π-electron systems have been reported, stable disilenes with heteroaromatic groups remain rare. Herein, we report the synthesis of monodisilenyl-substituted thiophene 1, anthracene 4, acridine 5, and mesitylene 7 and bis(disilenyl)-substituted thiophene 2, 2,2'-bithiophene 3, and anthracene 6via reactions of dialkylmesityldisilenide 8 with the corresponding haloarenes. Disilenes 1-7 show absorption bands with contributions of intramolecular charge transfer (ICT) transitions from π(disilene) to π*(aryl). In the ICT transitions, (bi)thienyl groups as well as anthryl and acrydinyl groups serve as electron acceptors for the Si[double bond, length as m-dash]Si double bonds." @default.
• W2745113048 created "2017-08-17" @default.
• W2745113048 creator A5013518524 @default.
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• W2745113048 date "2017-01-01" @default.
• W2745113048 modified "2023-10-18" @default.
• W2745113048 title "Heteroaryldisilenes: heteroaryl groups serve as electron acceptors for SiSi double bonds in intramolecular charge transfer transitions" @default.
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• W2745113048 doi "https://doi.org/10.1039/c7dt02357j" @default.
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